Oxidative cyclization reactions: Controlling the course of a radical cation-derived reaction with the use of a second nucleophile

Alison Redden; Robert J. Perkins; Kevin D. Moeller

doi:10.1002/anie.201308739

Oxidative cyclization reactions: Controlling the course of a radical cation-derived reaction with the use of a second nucleophile

Alison Redden
, Robert J. Perkins
, Kevin D. Moeller

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Construction of new ring systems: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether-derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.

Original language	English
Pages (from-to)	12865-12868
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	49
DOIs	https://doi.org/10.1002/anie.201308739
State	Published - Dec 2 2013

Keywords

anodic cyclizations
electrochemistry
radical ions
reactive intermediates

Access to Document

10.1002/anie.201308739

Cite this

@article{494817baa18a4d41afaa753381827ea9,

title = "Oxidative cyclization reactions: Controlling the course of a radical cation-derived reaction with the use of a second nucleophile",

abstract = "Construction of new ring systems: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether-derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.",

keywords = "anodic cyclizations, electrochemistry, radical ions, reactive intermediates",

author = "Alison Redden and Perkins, \{Robert J.\} and Moeller, \{Kevin D.\}",

year = "2013",

month = dec,

day = "2",

doi = "10.1002/anie.201308739",

language = "English",

volume = "52",

pages = "12865--12868",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

number = "49",

}

TY - JOUR

T1 - Oxidative cyclization reactions

T2 - Controlling the course of a radical cation-derived reaction with the use of a second nucleophile

AU - Redden, Alison

AU - Perkins, Robert J.

AU - Moeller, Kevin D.

PY - 2013/12/2

Y1 - 2013/12/2

N2 - Construction of new ring systems: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether-derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.

AB - Construction of new ring systems: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether-derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.

KW - anodic cyclizations

KW - electrochemistry

KW - radical ions

KW - reactive intermediates

UR - https://www.scopus.com/pages/publications/84888614801

U2 - 10.1002/anie.201308739

DO - 10.1002/anie.201308739

M3 - Article

C2 - 24254900

AN - SCOPUS:84888614801

SN - 1433-7851

VL - 52

SP - 12865

EP - 12868

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 49

ER -

Oxidative cyclization reactions: Controlling the course of a radical cation-derived reaction with the use of a second nucleophile

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this