When hot water freezes before cold

  • J. I. Katz

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

I suggest that the origin of the Mpemba effect (the freezing of hot water before cold) is due to freezing-point depression by solutes, either gaseous or solid, whose solubility decreases with increasing temperature so that they are removed when water is heated. The solutes are concentrated ahead of the freezing front by zone refining in water that has not been heated, reducing the temperature of the freezing front, and thereby reducing the temperature gradient and heat flux, slowing the progress of the freezing front. I present a simple calculation of this effect, and suggest experiments to test this hypothesis.

Original languageEnglish
Pages (from-to)27-29
Number of pages3
JournalAmerican Journal of Physics
Volume77
Issue number1
DOIs
StatePublished - 2009

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