Unified approach to substituted allenoates via Pd-catalyzed β-hydride elimination of (E)-enol triflates

Marie El Arba; Sara E. Dibrell; Ian T. Crouch; Doug E. Frantz

doi:10.1021/acs.orglett.7b02736

Unified approach to substituted allenoates via Pd-catalyzed β-hydride elimination of (E)-enol triflates

Marie El Arba
, Sara E. Dibrell
, Ian T. Crouch
, Doug E. Frantz

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A robust synthesis of allenoates via a Pdcatalyzed β-hydride elimination of (E)-enol triflates is presented. Salient features of this method include low catalyst loadings, mild reaction conditions, and the ability to access all four patterns of substituted allenoates from a single substrate class.

Original language	English
Pages (from-to)	5446-5449
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	19
DOIs	https://doi.org/10.1021/acs.orglett.7b02736
State	Published - Oct 6 2017

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title = "Unified approach to substituted allenoates via Pd-catalyzed β-hydride elimination of (E)-enol triflates",

abstract = "A robust synthesis of allenoates via a Pdcatalyzed β-hydride elimination of (E)-enol triflates is presented. Salient features of this method include low catalyst loadings, mild reaction conditions, and the ability to access all four patterns of substituted allenoates from a single substrate class.",

author = "\{El Arba\}, Marie and Dibrell, \{Sara E.\} and Crouch, \{Ian T.\} and Frantz, \{Doug E.\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/acs.orglett.7b02736",

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T1 - Unified approach to substituted allenoates via Pd-catalyzed β-hydride elimination of (E)-enol triflates

AU - El Arba, Marie

AU - Dibrell, Sara E.

AU - Crouch, Ian T.

AU - Frantz, Doug E.

PY - 2017/10/6

Y1 - 2017/10/6

N2 - A robust synthesis of allenoates via a Pdcatalyzed β-hydride elimination of (E)-enol triflates is presented. Salient features of this method include low catalyst loadings, mild reaction conditions, and the ability to access all four patterns of substituted allenoates from a single substrate class.

AB - A robust synthesis of allenoates via a Pdcatalyzed β-hydride elimination of (E)-enol triflates is presented. Salient features of this method include low catalyst loadings, mild reaction conditions, and the ability to access all four patterns of substituted allenoates from a single substrate class.

UR - https://www.scopus.com/pages/publications/85032645398

U2 - 10.1021/acs.orglett.7b02736

DO - 10.1021/acs.orglett.7b02736

M3 - Article

C2 - 28953409

AN - SCOPUS:85032645398

SN - 1523-7060

VL - 19

SP - 5446

EP - 5449

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Unified approach to substituted allenoates via Pd-catalyzed β-hydride elimination of (E)-enol triflates

Abstract

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