TY - JOUR
T1 - The synthesis, structure and properties of diazaphospholes
T2 - Reagents and ligands for asymmetric synthesis
AU - De La Cruz, Antonette
AU - Koeller, Kevin J.
AU - Rath, Nigam P.
AU - Spilling, Christopher D.
AU - Vasconcelos, Isabel C.F.
PY - 1998/8/27
Y1 - 1998/8/27
N2 - Reaction of C2 diamines with PCl3 and Et3N in toluene, followed by water or hydrogen sulfide, gave a series of cyclic phosphorous acid diamides (diazaphosphole oxides) and thiophosphorous acid diamides (diazaphosphole sulfides), respectively. Similarly, reaction of diamines with phenyl dichlorophosphine gave phenyl diazaphospholes. The synthesis, properties, and structure of these diazaphospholes are reported.
AB - Reaction of C2 diamines with PCl3 and Et3N in toluene, followed by water or hydrogen sulfide, gave a series of cyclic phosphorous acid diamides (diazaphosphole oxides) and thiophosphorous acid diamides (diazaphosphole sulfides), respectively. Similarly, reaction of diamines with phenyl dichlorophosphine gave phenyl diazaphospholes. The synthesis, properties, and structure of these diazaphospholes are reported.
UR - https://www.scopus.com/pages/publications/0032572849
U2 - 10.1016/S0040-4020(98)00502-X
DO - 10.1016/S0040-4020(98)00502-X
M3 - Article
AN - SCOPUS:0032572849
SN - 0040-4020
VL - 54
SP - 10513
EP - 10524
JO - Tetrahedron
JF - Tetrahedron
IS - 35
ER -