Synthesis, structure, and spectroscopy of (thiapentadienyl)rhodium phosphine complexes

John R. Bleeke; Eric S. Wise; Monica Shokeen; Nigam P. Rath

doi:10.1021/om040137o

Synthesis, structure, and spectroscopy of (thiapentadienyl)rhodium phosphine complexes

John R. Bleeke
, Eric S. Wise
, Monica Shokeen
, Nigam P. Rath

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The reactions of (Cl)Rh(PR ₃) ₃ (R = Me, Et) with the anionic thiapentadienide reagent lithium 2,3-dimethyl-5-thiapentadienide have been investigated. In each case, the kinetic product exhibits a thiapentadienyl bonding mode in which the sulfur atom is σ-bonded to rhodium; however, ligand rearrangement yields thermodynamic isomers in which the carbon end of the thiapentadienyl chain is σ-bonded to rhodium.

Original language	English
Pages (from-to)	805-808
Number of pages	4
Journal	Organometallics
Volume	24
Issue number	5
DOIs	https://doi.org/10.1021/om040137o
State	Published - Feb 28 2005

Access to Document

10.1021/om040137o

Cite this

@article{5b2afa6800494bb08a7916a4a4c6e659,

title = "Synthesis, structure, and spectroscopy of (thiapentadienyl)rhodium phosphine complexes",

abstract = "The reactions of (Cl)Rh(PR 3) 3 (R = Me, Et) with the anionic thiapentadienide reagent lithium 2,3-dimethyl-5-thiapentadienide have been investigated. In each case, the kinetic product exhibits a thiapentadienyl bonding mode in which the sulfur atom is σ-bonded to rhodium; however, ligand rearrangement yields thermodynamic isomers in which the carbon end of the thiapentadienyl chain is σ-bonded to rhodium.",

author = "Bleeke, \{John R.\} and Wise, \{Eric S.\} and Monica Shokeen and Rath, \{Nigam P.\}",

year = "2005",

month = feb,

day = "28",

doi = "10.1021/om040137o",

language = "English",

volume = "24",

pages = "805--808",

journal = "Organometallics",

issn = "0276-7333",

number = "5",

}

TY - JOUR

T1 - Synthesis, structure, and spectroscopy of (thiapentadienyl)rhodium phosphine complexes

AU - Bleeke, John R.

AU - Wise, Eric S.

AU - Shokeen, Monica

AU - Rath, Nigam P.

PY - 2005/2/28

Y1 - 2005/2/28

N2 - The reactions of (Cl)Rh(PR 3) 3 (R = Me, Et) with the anionic thiapentadienide reagent lithium 2,3-dimethyl-5-thiapentadienide have been investigated. In each case, the kinetic product exhibits a thiapentadienyl bonding mode in which the sulfur atom is σ-bonded to rhodium; however, ligand rearrangement yields thermodynamic isomers in which the carbon end of the thiapentadienyl chain is σ-bonded to rhodium.

AB - The reactions of (Cl)Rh(PR 3) 3 (R = Me, Et) with the anionic thiapentadienide reagent lithium 2,3-dimethyl-5-thiapentadienide have been investigated. In each case, the kinetic product exhibits a thiapentadienyl bonding mode in which the sulfur atom is σ-bonded to rhodium; however, ligand rearrangement yields thermodynamic isomers in which the carbon end of the thiapentadienyl chain is σ-bonded to rhodium.

UR - https://www.scopus.com/pages/publications/14844327775

U2 - 10.1021/om040137o

DO - 10.1021/om040137o

M3 - Article

AN - SCOPUS:14844327775

SN - 0276-7333

VL - 24

SP - 805

EP - 808

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Synthesis, structure, and spectroscopy of (thiapentadienyl)rhodium phosphine complexes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this