Synthesis, structure, and spectroscopy of silaallyl - and silapentadienyl - Iridium - Phosphine complexes

John R. Bleeke; Todsapon Thananatthanachon; Nigam P. Rath

doi:10.1021/om700487n

Synthesis, structure, and spectroscopy of silaallyl - and silapentadienyl - Iridium - Phosphine complexes

John R. Bleeke, Todsapon Thananatthanachon, Nigam P. Rath

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Silaallyl - and silapentadienyl - iridium - phosphine complexes have been synthesized via the reaction of "(Me)Ir-(PMe ₃) ₃" with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C - H bond activation to produce a five-membered iridasilacycle, C=C bond coordination to generate an η ^I,η ²-silapentadienyl ligand, and decomposition.

Original language	English
Pages (from-to)	3904-3907
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	16
DOIs	https://doi.org/10.1021/om700487n
State	Published - Jul 30 2007

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abstract = "Silaallyl - and silapentadienyl - iridium - phosphine complexes have been synthesized via the reaction of {"}(Me)Ir-(PMe 3) 3{"} with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C - H bond activation to produce a five-membered iridasilacycle, C=C bond coordination to generate an η I,η 2-silapentadienyl ligand, and decomposition.",

author = "Bleeke, {John R.} and Todsapon Thananatthanachon and Rath, {Nigam P.}",

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AU - Bleeke, John R.

AU - Thananatthanachon, Todsapon

AU - Rath, Nigam P.

PY - 2007/7/30

Y1 - 2007/7/30

N2 - Silaallyl - and silapentadienyl - iridium - phosphine complexes have been synthesized via the reaction of "(Me)Ir-(PMe 3) 3" with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C - H bond activation to produce a five-membered iridasilacycle, C=C bond coordination to generate an η I,η 2-silapentadienyl ligand, and decomposition.

AB - Silaallyl - and silapentadienyl - iridium - phosphine complexes have been synthesized via the reaction of "(Me)Ir-(PMe 3) 3" with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C - H bond activation to produce a five-membered iridasilacycle, C=C bond coordination to generate an η I,η 2-silapentadienyl ligand, and decomposition.

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U2 - 10.1021/om700487n

DO - 10.1021/om700487n

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ER -

Synthesis, structure, and spectroscopy of silaallyl - and silapentadienyl - Iridium - Phosphine complexes

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