Synthesis of Unsaturated Six-Membered Iridacycles from (Pentadienyl)iridium Precursors

John R. Bleeke; Alicia M. Rohde; Devran W. Boorsma

doi:10.1021/om00027a057

Synthesis of Unsaturated Six-Membered Iridacycles from (Pentadienyl)iridium Precursors

John R. Bleeke
, Alicia M. Rohde
, Devran W. Boorsma

Department of Chemistry

Research output: Contribution to journal › Comment/debate

13 Scopus citations

Abstract

An iridacyclohexene complex, [formula omitted] (4), and its irida-cyclohexadiene analogue, [formula omitted] (6), have been synthesized and spectroscopically characterized. These novel unsaturated six-membered metallacycles are obtained via synthetic routes that utilize pentadienide as the source of ring carbon atoms.

Original language	English
Pages (from-to)	970-974
Number of pages	5
Journal	Organometallics
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/om00027a057
State	Published - 1993

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@article{a23d4becfb7f40adbcac1e94006ed9ef,

title = "Synthesis of Unsaturated Six-Membered Iridacycles from (Pentadienyl)iridium Precursors",

abstract = "An iridacyclohexene complex, [formula omitted] (4), and its irida-cyclohexadiene analogue, [formula omitted] (6), have been synthesized and spectroscopically characterized. These novel unsaturated six-membered metallacycles are obtained via synthetic routes that utilize pentadienide as the source of ring carbon atoms.",

author = "Bleeke, \{John R.\} and Rohde, \{Alicia M.\} and Boorsma, \{Devran W.\}",

year = "1993",

doi = "10.1021/om00027a057",

language = "English",

volume = "12",

pages = "970--974",

journal = "Organometallics",

issn = "0276-7333",

number = "3",

}

TY - JOUR

T1 - Synthesis of Unsaturated Six-Membered Iridacycles from (Pentadienyl)iridium Precursors

AU - Bleeke, John R.

AU - Rohde, Alicia M.

AU - Boorsma, Devran W.

PY - 1993

Y1 - 1993

N2 - An iridacyclohexene complex, [formula omitted] (4), and its irida-cyclohexadiene analogue, [formula omitted] (6), have been synthesized and spectroscopically characterized. These novel unsaturated six-membered metallacycles are obtained via synthetic routes that utilize pentadienide as the source of ring carbon atoms.

AB - An iridacyclohexene complex, [formula omitted] (4), and its irida-cyclohexadiene analogue, [formula omitted] (6), have been synthesized and spectroscopically characterized. These novel unsaturated six-membered metallacycles are obtained via synthetic routes that utilize pentadienide as the source of ring carbon atoms.

UR - https://www.scopus.com/pages/publications/0040575871

U2 - 10.1021/om00027a057

DO - 10.1021/om00027a057

M3 - Comment/debate

AN - SCOPUS:0040575871

SN - 0276-7333

VL - 12

SP - 970

EP - 974

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Synthesis of Unsaturated Six-Membered Iridacycles from (Pentadienyl)iridium Precursors

Abstract

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