Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution

Wei Wang; Katherine M. Wentz; Sophia E. Hayes; Darren W. Johnson; Douglas A. Keszler

doi:10.1021/ic200483q

Synthesis of the hydroxide cluster [Al₁₃(μ₃-OH) ₆(μ-OH)₁₈(H₂O)₂₄]¹⁵⁺ from an aqueous solution

Wei Wang
, Katherine M. Wentz
, Sophia E. Hayes
, Darren W. Johnson
, Douglas A. Keszler

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

A scalable synthesis of the "flat" tridecameric inorganic cluster [Al₁₃(μ₃-OH)₆(μ-OH)₁₈(H ₂O)₂₄]¹⁵⁺ has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO₃)₃. Products have been characterized by X-ray diffraction and solid-state ²⁷Al MAS and MQMAS NMR.

Original language	English
Pages (from-to)	4683-4685
Number of pages	3
Journal	Inorganic Chemistry
Volume	50
Issue number	11
DOIs	https://doi.org/10.1021/ic200483q
State	Published - Jun 6 2011

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abstract = "A scalable synthesis of the {"}flat{"} tridecameric inorganic cluster [Al13(μ3-OH)6(μ-OH)18(H 2O)24]15+ has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55\% relative to the starting reagent Al(NO3)3. Products have been characterized by X-ray diffraction and solid-state 27Al MAS and MQMAS NMR.",

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AU - Wang, Wei

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AU - Hayes, Sophia E.

AU - Johnson, Darren W.

AU - Keszler, Douglas A.

PY - 2011/6/6

Y1 - 2011/6/6

N2 - A scalable synthesis of the "flat" tridecameric inorganic cluster [Al13(μ3-OH)6(μ-OH)18(H 2O)24]15+ has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO3)3. Products have been characterized by X-ray diffraction and solid-state 27Al MAS and MQMAS NMR.

AB - A scalable synthesis of the "flat" tridecameric inorganic cluster [Al13(μ3-OH)6(μ-OH)18(H 2O)24]15+ has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO3)3. Products have been characterized by X-ray diffraction and solid-state 27Al MAS and MQMAS NMR.

UR - https://www.scopus.com/pages/publications/79958107129

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Synthesis of the hydroxide cluster [Al₁₃(μ₃-OH) ₆(μ-OH)₁₈(H₂O)₂₄]¹⁵⁺ from an aqueous solution

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