Synthesis of ordered mesoporous Li-Mn-O spinel as a positive electrode for rechargeable lithium batteries

  • Feng Jiao
  • , Jianli Bao
  • , Adrian H. Hill
  • , Peter G. Bruce

Research output: Contribution to journalArticlepeer-review

218 Scopus citations

Abstract

(Figure Presented) Sturdy spinel: A mesoporous Li-Mn-O spinel (Li 1.12Mn1.88O4) with superior rate capability at ambient temperature is synthesized. Comparable stability to the bulk material at elevated temperatures is also observed, despite a surface area of 90 m 2g-1 for the mesopore, suggesting that the internal mesopore surfaces are more stable than the external surface.

Original languageEnglish
Pages (from-to)9711-9716
Number of pages6
JournalAngewandte Chemie - International Edition
Volume47
Issue number50
DOIs
StatePublished - Dec 1 2008

Keywords

  • Electrodes
  • Intercalation
  • Lithium batteries
  • Mesoporous materials
  • Spinel phases

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