Synthesis of acetone oxime through acetone ammoximation over TS-1

Xinhua Liang; Zhentao Mi; Yaquan Wang; Li Wang; Xiangwen Zhang

doi:10.1023/B:REAC.0000034845.65961.3e

Synthesis of acetone oxime through acetone ammoximation over TS-1

Xinhua Liang
, Zhentao Mi
, Yaquan Wang
, Li Wang
, Xiangwen Zhang

Department of Energy, Environmental & Chemical Engineering

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH₃ to acetone molar ratio were investigated.

Original language	English
Pages (from-to)	333-337
Number of pages	5
Journal	Reaction Kinetics and Catalysis Letters
Volume	82
Issue number	2
DOIs	https://doi.org/10.1023/B:REAC.0000034845.65961.3e
State	Published - 2004

Keywords

Acetone
Acetone oxime
Ammoximation
Hydrogen peroxide
TS-1

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10.1023/B:REAC.0000034845.65961.3e

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title = "Synthesis of acetone oxime through acetone ammoximation over TS-1",

abstract = "The ammoximation of acetone to acetone oxime with 30 wt.\% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99\% and 94\%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.",

keywords = "Acetone, Acetone oxime, Ammoximation, Hydrogen peroxide, TS-1",

author = "Xinhua Liang and Zhentao Mi and Yaquan Wang and Li Wang and Xiangwen Zhang",

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journal = "Reaction Kinetics and Catalysis Letters",

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T1 - Synthesis of acetone oxime through acetone ammoximation over TS-1

AU - Liang, Xinhua

AU - Mi, Zhentao

AU - Wang, Yaquan

AU - Wang, Li

AU - Zhang, Xiangwen

PY - 2004

Y1 - 2004

N2 - The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.

AB - The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.

KW - Acetone

KW - Acetone oxime

KW - Ammoximation

KW - Hydrogen peroxide

KW - TS-1

UR - https://www.scopus.com/pages/publications/3142682561

U2 - 10.1023/B:REAC.0000034845.65961.3e

DO - 10.1023/B:REAC.0000034845.65961.3e

M3 - Article

AN - SCOPUS:3142682561

SN - 0133-1736

VL - 82

SP - 333

EP - 337

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

Synthesis of acetone oxime through acetone ammoximation over TS-1

Abstract

Keywords

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