Synthesis, characterization, and reactions of chromyl(VI) alkoxides

Sunehri L. Chadha; Vijay Sharma; Anuradha Sharma

doi:10.1039/DT9870001253

Synthesis, characterization, and reactions of chromyl(VI) alkoxides

Sunehri L. Chadha, Vijay Sharma, Anuradha Sharma

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Abstract

Alkoxy-bridged chromyl(VI) alkoxides, [CrO₂(OR)₂] and [CrO₂Cl(OR)] (R = CH₂CCl₃, CH₂CF₃, or CH₂CH₂Cl), have been synthesized. They react with oxygen- and nitrogen-donor ligands to form adducts. The alkoxides and their adducts have been characterized by elemental analyses, cryoscopic studies, i.r., ¹H and ¹⁹F n.m.r., and mass spectra.

Original language	English
Pages (from-to)	1253-1255
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/DT9870001253
State	Published - 1987

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title = "Synthesis, characterization, and reactions of chromyl(VI) alkoxides",

abstract = "Alkoxy-bridged chromyl(VI) alkoxides, [CrO2(OR)2] and [CrO2Cl(OR)] (R = CH2CCl3, CH2CF3, or CH2CH2Cl), have been synthesized. They react with oxygen- and nitrogen-donor ligands to form adducts. The alkoxides and their adducts have been characterized by elemental analyses, cryoscopic studies, i.r., 1H and 19F n.m.r., and mass spectra.",

author = "Chadha, {Sunehri L.} and Vijay Sharma and Anuradha Sharma",

year = "1987",

doi = "10.1039/DT9870001253",

language = "English",

pages = "1253--1255",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

number = "5",

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TY - JOUR

T1 - Synthesis, characterization, and reactions of chromyl(VI) alkoxides

AU - Chadha, Sunehri L.

AU - Sharma, Vijay

AU - Sharma, Anuradha

PY - 1987

Y1 - 1987

N2 - Alkoxy-bridged chromyl(VI) alkoxides, [CrO2(OR)2] and [CrO2Cl(OR)] (R = CH2CCl3, CH2CF3, or CH2CH2Cl), have been synthesized. They react with oxygen- and nitrogen-donor ligands to form adducts. The alkoxides and their adducts have been characterized by elemental analyses, cryoscopic studies, i.r., 1H and 19F n.m.r., and mass spectra.

AB - Alkoxy-bridged chromyl(VI) alkoxides, [CrO2(OR)2] and [CrO2Cl(OR)] (R = CH2CCl3, CH2CF3, or CH2CH2Cl), have been synthesized. They react with oxygen- and nitrogen-donor ligands to form adducts. The alkoxides and their adducts have been characterized by elemental analyses, cryoscopic studies, i.r., 1H and 19F n.m.r., and mass spectra.

UR - http://www.scopus.com/inward/record.url?scp=37049080310&partnerID=8YFLogxK

U2 - 10.1039/DT9870001253

DO - 10.1039/DT9870001253

M3 - Article

AN - SCOPUS:37049080310

SN - 1472-7773

SP - 1253

EP - 1255

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 5

ER -

Synthesis, characterization, and reactions of chromyl(VI) alkoxides

Abstract

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