TY - JOUR
T1 - Structure and electronic properties of Pd(III) complexes
AU - Mirica, Liviu M.
AU - Khusnutdinova, Julia R.
N1 - Funding Information:
We thank the Department of Chemistry at Washington University , the American Chemical Society Petroleum Research Fund ( 49914-DNI3 ), and DOE Catalysis Science Program ( DE-FG02-11ER16254 ) for financial support. L.M.M. is a Sloan Fellow.
PY - 2013/1/5
Y1 - 2013/1/5
N2 - Despite the rich chemistry of palladium in oxidation states of 0, +2, and +4, no Pd III coordination compounds have been reported until the 1980s. Moreover, while Pd complexes are among the most commonly used catalysts in organometallic chemistry, the first organometallic Pd III complexes have only been reported in 2006. Since then, a significant number of Pd III complexes have been isolated, characterized, and proposed as active catalytic intermediates in the functionalization of CH bonds, oxidatively induced CC bond formation reactions, as well as radical insertion and addition reactions. This review provides an overview of the synthesis and spectroscopic characterization of mononuclear and dinuclear Pd III complexes. A detailed understanding of the steric and electronic properties of Pd III complexes should provide insight for the development of novel catalysts for multi-electron redox reactions and various organometallic transformations.
AB - Despite the rich chemistry of palladium in oxidation states of 0, +2, and +4, no Pd III coordination compounds have been reported until the 1980s. Moreover, while Pd complexes are among the most commonly used catalysts in organometallic chemistry, the first organometallic Pd III complexes have only been reported in 2006. Since then, a significant number of Pd III complexes have been isolated, characterized, and proposed as active catalytic intermediates in the functionalization of CH bonds, oxidatively induced CC bond formation reactions, as well as radical insertion and addition reactions. This review provides an overview of the synthesis and spectroscopic characterization of mononuclear and dinuclear Pd III complexes. A detailed understanding of the steric and electronic properties of Pd III complexes should provide insight for the development of novel catalysts for multi-electron redox reactions and various organometallic transformations.
KW - Chemical oxidation
KW - Dinuclear Pd(III) complexes
KW - Electrolysis
KW - EPR
KW - Mononuclear Pd(III) complexes
KW - Pd catalysis
UR - http://www.scopus.com/inward/record.url?scp=84870390394&partnerID=8YFLogxK
U2 - 10.1016/j.ccr.2012.04.030
DO - 10.1016/j.ccr.2012.04.030
M3 - Review article
AN - SCOPUS:84870390394
SN - 0010-8545
VL - 257
SP - 299
EP - 314
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
IS - 2
ER -