Stabilization of reactants in a weakly bound complex: OH-H2 and OH-D2

Richard A. Loomis; Marsha I. Lester

doi:10.1063/1.470678

Stabilization of reactants in a weakly bound complex: OH-H₂ and OH-D₂

Richard A. Loomis
, Marsha I. Lester

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Binary complexes of OH X²Π and H₂/D₂ have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH A ²Σ⁺-X ²Π 1-0 spectral region. The characteristics of the OH (X²Π, A ²Σ ₊)+H₂/D₂ potentials are in accord with ab initio predictions.

Original language	English
Pages (from-to)	4371-4374
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	103
Issue number	10
DOIs	https://doi.org/10.1063/1.470678
State	Published - 1995

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@article{26fbfc12b5cb43adb84022b2ec5bfcae,

title = "Stabilization of reactants in a weakly bound complex: OH-H2 and OH-D2",

abstract = "Binary complexes of OH X2Π and H2/D2 have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH A 2Σ+-X 2Π 1-0 spectral region. The characteristics of the OH (X2Π, A 2Σ +)+H2/D2 potentials are in accord with ab initio predictions.",

author = "Loomis, \{Richard A.\} and Lester, \{Marsha I.\}",

year = "1995",

doi = "10.1063/1.470678",

language = "English",

volume = "103",

pages = "4371--4374",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

number = "10",

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T1 - Stabilization of reactants in a weakly bound complex

T2 - OH-H2 and OH-D2

AU - Loomis, Richard A.

AU - Lester, Marsha I.

PY - 1995

Y1 - 1995

N2 - Binary complexes of OH X2Π and H2/D2 have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH A 2Σ+-X 2Π 1-0 spectral region. The characteristics of the OH (X2Π, A 2Σ +)+H2/D2 potentials are in accord with ab initio predictions.

AB - Binary complexes of OH X2Π and H2/D2 have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH A 2Σ+-X 2Π 1-0 spectral region. The characteristics of the OH (X2Π, A 2Σ +)+H2/D2 potentials are in accord with ab initio predictions.

UR - https://www.scopus.com/pages/publications/36449008410

U2 - 10.1063/1.470678

DO - 10.1063/1.470678

M3 - Article

AN - SCOPUS:36449008410

SN - 0021-9606

VL - 103

SP - 4371

EP - 4374

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 10

ER -

Stabilization of reactants in a weakly bound complex: OH-H₂ and OH-D₂

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