Spectroscopic observation of the preferentially stabilized, linear He⋯IC1(X 1Σ+) complex

Matthew D. Bradke; Richard A. Loomis

doi:10.1063/1.1562622

Spectroscopic observation of the preferentially stabilized, linear He⋯IC1(X ¹Σ⁺) complex

Matthew D. Bradke
, Richard A. Loomis

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

It is desirable to obtain experimental data for Rg-dihalogen complexes that characterize multiple intermolecular vibrational levels that sample varying regions of the intermolecular potential. This data can in turn be used to more thoroughly test the accuracy of the results obtained from advancing theoretical methods. The experimental results reported reveal laser-induced fluorescence (LIF) spectroscopy features attributable to rovibronic transitions from separately stabilized He⋯1^35,37Cl(X,v″=0) ground state complexes with nearly T-shaped and linear geometries in the IC1 B-X, 2-0 and 3-0 regions.

Original language	English
Pages (from-to)	7233-7244
Number of pages	12
Journal	Journal of Chemical Physics
Volume	118
Issue number	16
DOIs	https://doi.org/10.1063/1.1562622
State	Published - Apr 22 2003

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title = "Spectroscopic observation of the preferentially stabilized, linear He⋯IC1(X 1Σ+) complex",

abstract = "It is desirable to obtain experimental data for Rg-dihalogen complexes that characterize multiple intermolecular vibrational levels that sample varying regions of the intermolecular potential. This data can in turn be used to more thoroughly test the accuracy of the results obtained from advancing theoretical methods. The experimental results reported reveal laser-induced fluorescence (LIF) spectroscopy features attributable to rovibronic transitions from separately stabilized He⋯135,37Cl(X,v″=0) ground state complexes with nearly T-shaped and linear geometries in the IC1 B-X, 2-0 and 3-0 regions.",

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AU - Bradke, Matthew D.

AU - Loomis, Richard A.

PY - 2003/4/22

Y1 - 2003/4/22

N2 - It is desirable to obtain experimental data for Rg-dihalogen complexes that characterize multiple intermolecular vibrational levels that sample varying regions of the intermolecular potential. This data can in turn be used to more thoroughly test the accuracy of the results obtained from advancing theoretical methods. The experimental results reported reveal laser-induced fluorescence (LIF) spectroscopy features attributable to rovibronic transitions from separately stabilized He⋯135,37Cl(X,v″=0) ground state complexes with nearly T-shaped and linear geometries in the IC1 B-X, 2-0 and 3-0 regions.

AB - It is desirable to obtain experimental data for Rg-dihalogen complexes that characterize multiple intermolecular vibrational levels that sample varying regions of the intermolecular potential. This data can in turn be used to more thoroughly test the accuracy of the results obtained from advancing theoretical methods. The experimental results reported reveal laser-induced fluorescence (LIF) spectroscopy features attributable to rovibronic transitions from separately stabilized He⋯135,37Cl(X,v″=0) ground state complexes with nearly T-shaped and linear geometries in the IC1 B-X, 2-0 and 3-0 regions.

UR - https://www.scopus.com/pages/publications/0038737956

U2 - 10.1063/1.1562622

DO - 10.1063/1.1562622

M3 - Article

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SN - 0021-9606

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EP - 7244

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 16

ER -

Spectroscopic observation of the preferentially stabilized, linear He⋯IC1(X ¹Σ⁺) complex

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