Solvolytic behaviour and the solubilities of various inorganic compounds, lewis acids and bases in fused monobromo acetic acid solvent system-II

J. K. Puri; Jaswinder Kaur; Vijay Sharma; Jack M. Miller

doi:10.1016/S0277-5387(00)84388-0

Solvolytic behaviour and the solubilities of various inorganic compounds, lewis acids and bases in fused monobromo acetic acid solvent system-II

J. K. Puri, Jaswinder Kaur, Vijay Sharma, Jack M. Miller

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Solubilities and the solvolytic behaviour of various inorganic compounds, Lewis acids and bases in fused monobromoacetic acid at 60 ± 0.5°C are discussed. Ionic compounds are fairly soluble, iodides and thiocyanates being comparatively more soluble than chlorides and bromides. Tetraalkyl ammonium halides are highly soluble in this solvent. Conductometric and spectroscopic studies of various Lewis acids and bases in fused monobromoacetic acid indicate their solvolytic behaviour and their subsequent ionization. The solvolyses products BBr₃·CH₂BrCOOH and SbCl₅·CH₂BrCOOH have been observed to be the strongest Bronsted acids. Auto-ionization of this solvent has been supported by acid/base titrations.

Original language	English
Pages (from-to)	1287-1295
Number of pages	9
Journal	Polyhedron
Volume	2
Issue number	12
DOIs	https://doi.org/10.1016/S0277-5387(00)84388-0
State	Published - 1983

Access to Document

10.1016/S0277-5387(00)84388-0

Cite this

@article{6d4b6d5a4eed4c2aab21281b17ca299b,

title = "Solvolytic behaviour and the solubilities of various inorganic compounds, lewis acids and bases in fused monobromo acetic acid solvent system-II",

abstract = "Solubilities and the solvolytic behaviour of various inorganic compounds, Lewis acids and bases in fused monobromoacetic acid at 60 ± 0.5°C are discussed. Ionic compounds are fairly soluble, iodides and thiocyanates being comparatively more soluble than chlorides and bromides. Tetraalkyl ammonium halides are highly soluble in this solvent. Conductometric and spectroscopic studies of various Lewis acids and bases in fused monobromoacetic acid indicate their solvolytic behaviour and their subsequent ionization. The solvolyses products BBr3·CH2BrCOOH and SbCl5·CH2BrCOOH have been observed to be the strongest Bronsted acids. Auto-ionization of this solvent has been supported by acid/base titrations.",

author = "Puri, {J. K.} and Jaswinder Kaur and Vijay Sharma and Miller, {Jack M.}",

year = "1983",

doi = "10.1016/S0277-5387(00)84388-0",

language = "English",

volume = "2",

pages = "1287--1295",

journal = "Polyhedron",

issn = "0277-5387",

number = "12",

}

TY - JOUR

T1 - Solvolytic behaviour and the solubilities of various inorganic compounds, lewis acids and bases in fused monobromo acetic acid solvent system-II

AU - Puri, J. K.

AU - Kaur, Jaswinder

AU - Sharma, Vijay

AU - Miller, Jack M.

PY - 1983

Y1 - 1983

N2 - Solubilities and the solvolytic behaviour of various inorganic compounds, Lewis acids and bases in fused monobromoacetic acid at 60 ± 0.5°C are discussed. Ionic compounds are fairly soluble, iodides and thiocyanates being comparatively more soluble than chlorides and bromides. Tetraalkyl ammonium halides are highly soluble in this solvent. Conductometric and spectroscopic studies of various Lewis acids and bases in fused monobromoacetic acid indicate their solvolytic behaviour and their subsequent ionization. The solvolyses products BBr3·CH2BrCOOH and SbCl5·CH2BrCOOH have been observed to be the strongest Bronsted acids. Auto-ionization of this solvent has been supported by acid/base titrations.

AB - Solubilities and the solvolytic behaviour of various inorganic compounds, Lewis acids and bases in fused monobromoacetic acid at 60 ± 0.5°C are discussed. Ionic compounds are fairly soluble, iodides and thiocyanates being comparatively more soluble than chlorides and bromides. Tetraalkyl ammonium halides are highly soluble in this solvent. Conductometric and spectroscopic studies of various Lewis acids and bases in fused monobromoacetic acid indicate their solvolytic behaviour and their subsequent ionization. The solvolyses products BBr3·CH2BrCOOH and SbCl5·CH2BrCOOH have been observed to be the strongest Bronsted acids. Auto-ionization of this solvent has been supported by acid/base titrations.

UR - http://www.scopus.com/inward/record.url?scp=0038947415&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)84388-0

DO - 10.1016/S0277-5387(00)84388-0

M3 - Article

AN - SCOPUS:0038947415

SN - 0277-5387

VL - 2

SP - 1287

EP - 1295

JO - Polyhedron

JF - Polyhedron

IS - 12

ER -

Solvolytic behaviour and the solubilities of various inorganic compounds, lewis acids and bases in fused monobromo acetic acid solvent system-II

Abstract

Access to Document

Other files and links

Fingerprint

Cite this