Size- and shape-controlled synthesis of bismuth nanoparticles

Fudong Wang; Rui Tang; Heng Yu; Patrick C. Gibbons; William E. Buhro

doi:10.1021/cm8004425

Size- and shape-controlled synthesis of bismuth nanoparticles

Fudong Wang, Rui Tang, Heng Yu, Patrick C. Gibbons, William E. Buhro

Research output: Contribution to journal › Article › peer-review

156 Scopus citations

Abstract

Near-monodisperse Bi dots in the diameter range of 3- 115 nm are synthesized by a simple, solution-based one-step approach by varying the amounts of Bi[N(SiMe₃)₂]₃, Na[N(SiMe₃) ₂], and a polymer surfactant, poly(1-hexadecene)_0.67-co- (1-vinylpyrrolidinone)_0.33, employed. The reaction conditions are further modified to produce Bi nanorods and nanoplates. Alternatively, near-monodisperse Bi dots in the diameter range of 30-45 nm are synthesized by a secondary-addition technique. With a slight modification of this technique, nanoribbons are obtained. The roles of polymer and Na[N(SiMe₃) ₂] in the size and shape control of these Bi nanoparticles are discussed.

Original language	English
Pages (from-to)	3656-3662
Number of pages	7
Journal	Chemistry of Materials
Volume	20
Issue number	11
DOIs	https://doi.org/10.1021/cm8004425
State	Published - Jun 10 2008

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title = "Size- and shape-controlled synthesis of bismuth nanoparticles",

abstract = "Near-monodisperse Bi dots in the diameter range of 3- 115 nm are synthesized by a simple, solution-based one-step approach by varying the amounts of Bi[N(SiMe3)2]3, Na[N(SiMe3) 2], and a polymer surfactant, poly(1-hexadecene)0.67-co- (1-vinylpyrrolidinone)0.33, employed. The reaction conditions are further modified to produce Bi nanorods and nanoplates. Alternatively, near-monodisperse Bi dots in the diameter range of 30-45 nm are synthesized by a secondary-addition technique. With a slight modification of this technique, nanoribbons are obtained. The roles of polymer and Na[N(SiMe3) 2] in the size and shape control of these Bi nanoparticles are discussed.",

author = "Fudong Wang and Rui Tang and Heng Yu and Gibbons, {Patrick C.} and Buhro, {William E.}",

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T1 - Size- and shape-controlled synthesis of bismuth nanoparticles

AU - Wang, Fudong

AU - Tang, Rui

AU - Yu, Heng

AU - Gibbons, Patrick C.

AU - Buhro, William E.

PY - 2008/6/10

Y1 - 2008/6/10

N2 - Near-monodisperse Bi dots in the diameter range of 3- 115 nm are synthesized by a simple, solution-based one-step approach by varying the amounts of Bi[N(SiMe3)2]3, Na[N(SiMe3) 2], and a polymer surfactant, poly(1-hexadecene)0.67-co- (1-vinylpyrrolidinone)0.33, employed. The reaction conditions are further modified to produce Bi nanorods and nanoplates. Alternatively, near-monodisperse Bi dots in the diameter range of 30-45 nm are synthesized by a secondary-addition technique. With a slight modification of this technique, nanoribbons are obtained. The roles of polymer and Na[N(SiMe3) 2] in the size and shape control of these Bi nanoparticles are discussed.

AB - Near-monodisperse Bi dots in the diameter range of 3- 115 nm are synthesized by a simple, solution-based one-step approach by varying the amounts of Bi[N(SiMe3)2]3, Na[N(SiMe3) 2], and a polymer surfactant, poly(1-hexadecene)0.67-co- (1-vinylpyrrolidinone)0.33, employed. The reaction conditions are further modified to produce Bi nanorods and nanoplates. Alternatively, near-monodisperse Bi dots in the diameter range of 30-45 nm are synthesized by a secondary-addition technique. With a slight modification of this technique, nanoribbons are obtained. The roles of polymer and Na[N(SiMe3) 2] in the size and shape control of these Bi nanoparticles are discussed.

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Size- and shape-controlled synthesis of bismuth nanoparticles

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