TY - JOUR
T1 - Simplified analysis of chlorinated ethenes in water samples by gas chromatography with flame ionization detection
AU - Ticknor, Jonathan L.
AU - Elsayed-Ali, Omar
AU - Kim, Won Seok
AU - Trotz, Maya A.
AU - Cunningham, Jeffrey A.
PY - 2013/1/1
Y1 - 2013/1/1
N2 - Chlorinated ethenes are among the most common environmental contaminants and are known or suspected carcinogens. This class of compounds includes perchloroethene (PCE), trichloroethene (TCE), and their breakdown products, including dichloroethene (DCE) isomers and vinyl chloride (VC). Engineers and scientists must be able to measure concentrations of these chemicals in water samples to assess site contamination, monitor clean-up progress, and test possible remediation technologies. Gas chromatography with flame ionization detection (GC/FID) is a common method for measuring these contaminants in environmental samples. In this study, we tested the hypothesis that FID response factors are equal for all chlorinated ethene compounds. The rationale for the investigation was that if the hypothesis is correct, a single calibration curve can be used for GC/FID analysis of all chlorinated ethene compounds, saving time and money during sample analysis. Based on our measurements, a single calibration curve (FID response versus mass of analyte injected) is applicable to analysis of PCE, TCE, and all three DCE isomers (r2=0.990, n=50 measurements), allowing for simplified quantification of those chemicals. However, the apparent FID response factor for VC was lower by ∼40%, indicating that a separate calibration curve would need to be used to accurately estimate the VC concentration in water samples. The difference in the apparent VC response factor is caused predominantly by losses of VC to volatilization during the analysis.
AB - Chlorinated ethenes are among the most common environmental contaminants and are known or suspected carcinogens. This class of compounds includes perchloroethene (PCE), trichloroethene (TCE), and their breakdown products, including dichloroethene (DCE) isomers and vinyl chloride (VC). Engineers and scientists must be able to measure concentrations of these chemicals in water samples to assess site contamination, monitor clean-up progress, and test possible remediation technologies. Gas chromatography with flame ionization detection (GC/FID) is a common method for measuring these contaminants in environmental samples. In this study, we tested the hypothesis that FID response factors are equal for all chlorinated ethene compounds. The rationale for the investigation was that if the hypothesis is correct, a single calibration curve can be used for GC/FID analysis of all chlorinated ethene compounds, saving time and money during sample analysis. Based on our measurements, a single calibration curve (FID response versus mass of analyte injected) is applicable to analysis of PCE, TCE, and all three DCE isomers (r2=0.990, n=50 measurements), allowing for simplified quantification of those chemicals. However, the apparent FID response factor for VC was lower by ∼40%, indicating that a separate calibration curve would need to be used to accurately estimate the VC concentration in water samples. The difference in the apparent VC response factor is caused predominantly by losses of VC to volatilization during the analysis.
KW - chlorinated ethenes
KW - flame ionization
KW - gas chromatography
KW - ground water
KW - headspace
KW - response factor
UR - http://www.scopus.com/inward/record.url?scp=84874091743&partnerID=8YFLogxK
U2 - 10.1089/ees.2012.0101
DO - 10.1089/ees.2012.0101
M3 - Article
AN - SCOPUS:84874091743
SN - 1092-8758
VL - 30
SP - 30
EP - 37
JO - Environmental Engineering Science
JF - Environmental Engineering Science
IS - 1
ER -