Ru(II)-Catalyzed Synthesis of Substituted Furans and Their Conversion to Butenolides

Marie El Arba; Sara E. Dibrell; Frederick Meece; Doug E. Frantz

doi:10.1021/acs.orglett.8b02554

Ru(II)-Catalyzed Synthesis of Substituted Furans and Their Conversion to Butenolides

Marie El Arba
, Sara E. Dibrell
, Frederick Meece
, Doug E. Frantz

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The synthesis of densely functionalized trisubstituted and tetrasubstituted furans via a novel Ru(II)-catalyzed intramolecular cyclization of vinyl diazoesters is reported. The synthetic utility of these furans is further demonstrated through a simple acid-mediated reaction to access highly substituted δalpha;,β-butenolides.

Original language	English
Pages (from-to)	5886-5888
Number of pages	3
Journal	Organic Letters
Volume	20
Issue number	18
DOIs	https://doi.org/10.1021/acs.orglett.8b02554
State	Published - Sep 21 2018

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title = "Ru(II)-Catalyzed Synthesis of Substituted Furans and Their Conversion to Butenolides",

abstract = "The synthesis of densely functionalized trisubstituted and tetrasubstituted furans via a novel Ru(II)-catalyzed intramolecular cyclization of vinyl diazoesters is reported. The synthetic utility of these furans is further demonstrated through a simple acid-mediated reaction to access highly substituted δalpha;,β-butenolides.",

author = "\{El Arba\}, Marie and Dibrell, \{Sara E.\} and Frederick Meece and Frantz, \{Doug E.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = sep,

day = "21",

doi = "10.1021/acs.orglett.8b02554",

language = "English",

volume = "20",

pages = "5886--5888",

journal = "Organic Letters",

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T1 - Ru(II)-Catalyzed Synthesis of Substituted Furans and Their Conversion to Butenolides

AU - El Arba, Marie

AU - Dibrell, Sara E.

AU - Meece, Frederick

AU - Frantz, Doug E.

PY - 2018/9/21

Y1 - 2018/9/21

N2 - The synthesis of densely functionalized trisubstituted and tetrasubstituted furans via a novel Ru(II)-catalyzed intramolecular cyclization of vinyl diazoesters is reported. The synthetic utility of these furans is further demonstrated through a simple acid-mediated reaction to access highly substituted δalpha;,β-butenolides.

AB - The synthesis of densely functionalized trisubstituted and tetrasubstituted furans via a novel Ru(II)-catalyzed intramolecular cyclization of vinyl diazoesters is reported. The synthetic utility of these furans is further demonstrated through a simple acid-mediated reaction to access highly substituted δalpha;,β-butenolides.

UR - https://www.scopus.com/pages/publications/85053607164

U2 - 10.1021/acs.orglett.8b02554

DO - 10.1021/acs.orglett.8b02554

M3 - Article

C2 - 30204453

AN - SCOPUS:85053607164

SN - 1523-7060

VL - 20

SP - 5886

EP - 5888

JO - Organic Letters

JF - Organic Letters

IS - 18

ER -

Ru(II)-Catalyzed Synthesis of Substituted Furans and Their Conversion to Butenolides

Abstract

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