Recueil des Travaux Chimiques des Pays‐Bas Journal of the Royal Netherlands Chemical Society: General method for the synthesis of 3′,5′‐diesters and 2′‐acetals of the four common nucleosides

J. H. van Boom, P. M.J. Burgers, C. A.G. Haasnoot, C. B. Reese

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

A procedure suitable for the preparation on a large scale of 5′‐O‐(methoxyacetyl)‐3′‐O‐propionylribonucleosides (9a‐d) from each of the four main ribonucleosides 6a‐d has been developed. The usefulness of 9a‐d as starting products for the synthesis of crystalline 2′‐O‐(methoxytetrahydropyranyl)‐ribonucleosides (11a‐d), which are key intermediates in the synthesis of oligoribonucleotides, has been demonstrated.

Original languageEnglish
Pages (from-to)91-95
Number of pages5
JournalRecueil des Travaux Chimiques des Pays‐Bas
Volume96
Issue number4
DOIs
StatePublished - 1977

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