Reactions of Recoil Bromine Formed by the 76,77Kr→76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions

James J. Frost; Stephen M. Moerlein; Michael J. Welch

doi:10.1021/ja00405a007

Reactions of Recoil Bromine Formed by the ^76,77Kr→^76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions

James J. Frost, Stephen M. Moerlein, Michael J. Welch

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Bromine atoms formed by the systems ⁷⁶Kr→⁷⁶Br and ⁷⁷Kr→ ⁷⁷Br were allowed to react with simple hydrocarbons in the solid phase at 77 K and the products of the reactions studied. The product distributions for the two systems varied greatly, and these variations are discussed in terms of the charge and kinetic energy of the two recoiling bromine species. It is concluded that the product differences are due to altered radical environments arising from charge neutralization for ⁷⁶Br and recoil energy dissipation for ⁷⁷Br.

Original language	English
Pages (from-to)	4332-4337
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	103
Issue number	15
DOIs	https://doi.org/10.1021/ja00405a007
State	Published - Jul 1981

Access to Document

10.1021/ja00405a007

Cite this

@article{9a67d947f2c849918fd0c2850ca0e529,

title = "Reactions of Recoil Bromine Formed by the 76,77Kr→76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions",

abstract = "Bromine atoms formed by the systems 76Kr→76Br and 77Kr→ 77Br were allowed to react with simple hydrocarbons in the solid phase at 77 K and the products of the reactions studied. The product distributions for the two systems varied greatly, and these variations are discussed in terms of the charge and kinetic energy of the two recoiling bromine species. It is concluded that the product differences are due to altered radical environments arising from charge neutralization for 76Br and recoil energy dissipation for 77Br.",

author = "Frost, {James J.} and Moerlein, {Stephen M.} and Welch, {Michael J.}",

year = "1981",

month = jul,

doi = "10.1021/ja00405a007",

language = "English",

volume = "103",

pages = "4332--4337",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

number = "15",

}

TY - JOUR

T1 - Reactions of Recoil Bromine Formed by the 76,77Kr→76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions

AU - Frost, James J.

AU - Moerlein, Stephen M.

AU - Welch, Michael J.

PY - 1981/7

Y1 - 1981/7

N2 - Bromine atoms formed by the systems 76Kr→76Br and 77Kr→ 77Br were allowed to react with simple hydrocarbons in the solid phase at 77 K and the products of the reactions studied. The product distributions for the two systems varied greatly, and these variations are discussed in terms of the charge and kinetic energy of the two recoiling bromine species. It is concluded that the product differences are due to altered radical environments arising from charge neutralization for 76Br and recoil energy dissipation for 77Br.

AB - Bromine atoms formed by the systems 76Kr→76Br and 77Kr→ 77Br were allowed to react with simple hydrocarbons in the solid phase at 77 K and the products of the reactions studied. The product distributions for the two systems varied greatly, and these variations are discussed in terms of the charge and kinetic energy of the two recoiling bromine species. It is concluded that the product differences are due to altered radical environments arising from charge neutralization for 76Br and recoil energy dissipation for 77Br.

UR - http://www.scopus.com/inward/record.url?scp=33845556860&partnerID=8YFLogxK

U2 - 10.1021/ja00405a007

DO - 10.1021/ja00405a007

M3 - Article

AN - SCOPUS:33845556860

SN - 0002-7863

VL - 103

SP - 4332

EP - 4337

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

Reactions of Recoil Bromine Formed by the ^76,77Kr→^76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this