Reactions of Recoil Bromine Formed by the 76,77Kr→76,77Br Systems with Simple Hydrocarbons. Solid-Phase Reactions

James J. Frost, Stephen M. Moerlein, Michael J. Welch

Research output: Contribution to journalArticle

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Abstract

Bromine atoms formed by the systems 76Kr→76Br and 77Kr→ 77Br were allowed to react with simple hydrocarbons in the solid phase at 77 K and the products of the reactions studied. The product distributions for the two systems varied greatly, and these variations are discussed in terms of the charge and kinetic energy of the two recoiling bromine species. It is concluded that the product differences are due to altered radical environments arising from charge neutralization for 76Br and recoil energy dissipation for 77Br.

Original languageEnglish
Pages (from-to)4332-4337
Number of pages6
JournalJournal of the American Chemical Society
Volume103
Issue number15
DOIs
StatePublished - Jul 1981

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