Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Alan M. Spool; Karen A. Daube; Thomas E. Mallouk; James A. Belmont; Mark S. Wrighton

doi:10.1021/ja00271a083

Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Alan M. Spool
, Karen A. Daube
, Thomas E. Mallouk
, James A. Belmont
, Mark S. Wrighton

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

Original language	English
Pages (from-to)	3155-3157
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	108
Issue number	11
DOIs	https://doi.org/10.1021/ja00271a083
State	Published - 1986

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title = "Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face",

abstract = "We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.",

author = "Spool, \{Alan M.\} and Daube, \{Karen A.\} and Mallouk, \{Thomas E.\} and Belmont, \{James A.\} and Wrighton, \{Mark S.\}",

year = "1986",

doi = "10.1021/ja00271a083",

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pages = "3155--3157",

journal = "Journal of the American Chemical Society",

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T2 - Evidence for Selective Reaction of the P-Rich Face

AU - Spool, Alan M.

AU - Daube, Karen A.

AU - Mallouk, Thomas E.

AU - Belmont, James A.

AU - Wrighton, Mark S.

PY - 1986

Y1 - 1986

N2 - We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

AB - We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

UR - https://www.scopus.com/pages/publications/0010061032

U2 - 10.1021/ja00271a083

DO - 10.1021/ja00271a083

M3 - Article

AN - SCOPUS:0010061032

SN - 0002-7863

VL - 108

SP - 3155

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 11

ER -

Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Abstract

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