Rapid water disinfection using vertically aligned MoS₂ nanofilms and visible light

Solar energy is readily available in most climates and can be used for water purification. However, solar disinfection of drinking water mostly relies on ultraviolet light, which represents only 4% of the total solar energy, and this leads to a slow treatment speed. Therefore, the development of new materials that can harvest visible light for water disinfection, and so speed up solar water purification, is highly desirable. Here we show that few-layered vertically aligned MoS₂ (FLV-MoS₂) films can be used to harvest the whole spectrum of visible light (∼50% of solar energy) and achieve highly efficient water disinfection. The bandgap of MoS₂ was increased from 1.3 to 1.55eV by decreasing the domain size, which allowed the FLV-MoS₂ to generate reactive oxygen species (ROS) for bacterial inactivation in the water. The FLV-MoS₂ showed a ∼15 times better log inactivation efficiency of the indicator bacteria compared with that of bulk MoS₂, and a much faster inactivation of bacteria under both visible light and sunlight illumination compared with the widely used TiO₂. Moreover, by using a 5nm copper film on top of the FLV-MoS₂ as a catalyst to facilitate electron-hole pair separation and promote the generation of ROS, the disinfection rate was increased a further sixfold. With our approach, we achieved water disinfection of >99.999% inactivation of bacteria in 20min with a small amount of material (1.6mgl -1) under simulated visible light.