Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid

J. K. Puri; Jaswinder Kaur; Vijay Sharma; Jack M. Miller

doi:10.1016/S0277-5387(00)84113-3

Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid

J. K. Puri
, Jaswinder Kaur
, Vijay Sharma
, Jack M. Miller

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier¹ as, 2CH₂BrCOOH ⇌ CH₂BrCOOH₂⁺+ CH₂BrCOO^-.

Original language	English
Pages (from-to)	1253-1257
Number of pages	5
Journal	Polyhedron
Volume	4
Issue number	7
DOIs	https://doi.org/10.1016/S0277-5387(00)84113-3
State	Published - 1985

Access to Document

10.1016/S0277-5387(00)84113-3

Cite this

@article{9493385e13d54b50b3f1b5bf55ced413,

title = "Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid",

abstract = "Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier1 as, 2CH2BrCOOH ⇌ CH2BrCOOH2++ CH2BrCOO-.",

author = "Puri, \{J. K.\} and Jaswinder Kaur and Vijay Sharma and Miller, \{Jack M.\}",

note = "Funding Information: Acknowledgements-Thea uthors thank the Natural Sciencea nd EngineeringC ouncil of Canadaf or financial support to (J.M.M.) and the Panjab University, Chandigarh,I ndia for granto f leavet o J.K.P.",

year = "1985",

doi = "10.1016/S0277-5387(00)84113-3",

language = "English",

volume = "4",

pages = "1253--1257",

journal = "Polyhedron",

issn = "0277-5387",

number = "7",

}

TY - JOUR

T1 - Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid

AU - Puri, J. K.

AU - Kaur, Jaswinder

AU - Sharma, Vijay

AU - Miller, Jack M.

N1 - Funding Information: Acknowledgements-Thea uthors thank the Natural Sciencea nd EngineeringC ouncil of Canadaf or financial support to (J.M.M.) and the Panjab University, Chandigarh,I ndia for granto f leavet o J.K.P.

PY - 1985

Y1 - 1985

N2 - Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier1 as, 2CH2BrCOOH ⇌ CH2BrCOOH2++ CH2BrCOO-.

AB - Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier1 as, 2CH2BrCOOH ⇌ CH2BrCOOH2++ CH2BrCOO-.

UR - https://www.scopus.com/pages/publications/0040131586

U2 - 10.1016/S0277-5387(00)84113-3

DO - 10.1016/S0277-5387(00)84113-3

M3 - Article

AN - SCOPUS:0040131586

SN - 0277-5387

VL - 4

SP - 1253

EP - 1257

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid

Abstract

Access to Document

Other files and links

Fingerprint

Cite this