TY - JOUR
T1 - Preparation of metal bromoacetates from other salts by Solvolytic reactions in fused monobromoacetic acid
AU - Puri, J. K.
AU - Kaur, Jaswinder
AU - Sharma, Vijay
AU - Miller, Jack M.
N1 - Funding Information:
Acknowledgements-Thea uthors thank the Natural Sciencea nd EngineeringC ouncil of Canadaf or financial support to (J.M.M.) and the Panjab University, Chandigarh,I ndia for granto f leavet o J.K.P.
PY - 1985
Y1 - 1985
N2 - Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier1 as, 2CH2BrCOOH ⇌ CH2BrCOOH2++ CH2BrCOO-.
AB - Solvolytic reactions between monobromoacetic acid and metal oxides, carbonates, oxalates, formates, sulphites, nitrates, nitrites and chlorides form monobromoacetates. In the case of transition metals, a molecule of solvent is also attached to the solvolysed products. The solvolysed products have been investigated by IR, magnetic susceptibility and molar conductance measurements. Lewis bases form adducts with these products. The solvolytic reactions have been explained on the bases of autoionization of monobromoacetic acid reported earlier1 as, 2CH2BrCOOH ⇌ CH2BrCOOH2++ CH2BrCOO-.
UR - http://www.scopus.com/inward/record.url?scp=0040131586&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(00)84113-3
DO - 10.1016/S0277-5387(00)84113-3
M3 - Article
AN - SCOPUS:0040131586
SN - 0277-5387
VL - 4
SP - 1253
EP - 1257
JO - Polyhedron
JF - Polyhedron
IS - 7
ER -