Practical synthesis of oligosaccharides. Partial synthesis of avermectin B(1a)

K. C. Nicolaou; R. E. Dolle; D. P. Papahatjis; J. L. Randall

doi:10.1021/ja00327a021

Practical synthesis of oligosaccharides. Partial synthesis of avermectin B(1a)

K. C. Nicolaou, R. E. Dolle, D. P. Papahatjis, J. L. Randall

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331 Scopus citations

Abstract

A practical synthesis of oligosaccharides from phenylthio sugars via glycosyl fluorides is described. The new technology is applied to the synthesis of hexasaccharide 9 from a glucose derivative and avermectin B_1a(11) from an avermectin B_1aaglycon derivative.

Original language	English
Pages (from-to)	4189-4192
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	106
Issue number	15
DOIs	https://doi.org/10.1021/ja00327a021
State	Published - Jan 1 1984

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@article{cfc300110d074e87b415102cb32e113a,

title = "Practical synthesis of oligosaccharides. Partial synthesis of avermectin B(1a)",

abstract = "A practical synthesis of oligosaccharides from phenylthio sugars via glycosyl fluorides is described. The new technology is applied to the synthesis of hexasaccharide 9 from a glucose derivative and avermectin B1a(11) from an avermectin B1aaglycon derivative.",

author = "Nicolaou, {K. C.} and Dolle, {R. E.} and Papahatjis, {D. P.} and Randall, {J. L.}",

year = "1984",

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T1 - Practical synthesis of oligosaccharides. Partial synthesis of avermectin B(1a)

AU - Nicolaou, K. C.

AU - Dolle, R. E.

AU - Papahatjis, D. P.

AU - Randall, J. L.

PY - 1984/1/1

Y1 - 1984/1/1

N2 - A practical synthesis of oligosaccharides from phenylthio sugars via glycosyl fluorides is described. The new technology is applied to the synthesis of hexasaccharide 9 from a glucose derivative and avermectin B1a(11) from an avermectin B1aaglycon derivative.

AB - A practical synthesis of oligosaccharides from phenylthio sugars via glycosyl fluorides is described. The new technology is applied to the synthesis of hexasaccharide 9 from a glucose derivative and avermectin B1a(11) from an avermectin B1aaglycon derivative.

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U2 - 10.1021/ja00327a021

DO - 10.1021/ja00327a021

M3 - Article

AN - SCOPUS:0021135638

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EP - 4192

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

Practical synthesis of oligosaccharides. Partial synthesis of avermectin B(1a)

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