Porous organic crystals crosslinked by free-radical reactions

Krishanu Samanta; Jiashan Mi; Albert D. Chen; Fangzhou Li; Richard J. Staples; Aaron J. Rossini; Chenfeng Ke

doi:10.1039/d4cc02454k

Porous organic crystals crosslinked by free-radical reactions

Krishanu Samanta
, Jiashan Mi
, Albert D. Chen
, Fangzhou Li
, Richard J. Staples
, Aaron J. Rossini
, Chenfeng Ke

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two hydrogen-bonded crosslinked organic frameworks (H_COFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These H_COFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich H_COFs was converted to a hydroxylated framework through hydroboration-oxidation while maintaining the high crystallinity.

Original language	English
Pages (from-to)	7311-7314
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	57
DOIs	https://doi.org/10.1039/d4cc02454k
State	Published - Jun 24 2024

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title = "Porous organic crystals crosslinked by free-radical reactions",

abstract = "Two hydrogen-bonded crosslinked organic frameworks (HCOFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These HCOFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich HCOFs was converted to a hydroxylated framework through hydroboration-oxidation while maintaining the high crystallinity.",

author = "Krishanu Samanta and Jiashan Mi and Chen, \{Albert D.\} and Fangzhou Li and Staples, \{Richard J.\} and Rossini, \{Aaron J.\} and Chenfeng Ke",

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T1 - Porous organic crystals crosslinked by free-radical reactions

AU - Samanta, Krishanu

AU - Mi, Jiashan

AU - Chen, Albert D.

AU - Li, Fangzhou

AU - Staples, Richard J.

AU - Rossini, Aaron J.

AU - Ke, Chenfeng

PY - 2024/6/24

Y1 - 2024/6/24

N2 - Two hydrogen-bonded crosslinked organic frameworks (HCOFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These HCOFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich HCOFs was converted to a hydroxylated framework through hydroboration-oxidation while maintaining the high crystallinity.

AB - Two hydrogen-bonded crosslinked organic frameworks (HCOFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These HCOFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich HCOFs was converted to a hydroxylated framework through hydroboration-oxidation while maintaining the high crystallinity.

UR - https://www.scopus.com/pages/publications/85197865316

U2 - 10.1039/d4cc02454k

DO - 10.1039/d4cc02454k

M3 - Article

C2 - 38912870

AN - SCOPUS:85197865316

SN - 1359-7345

VL - 60

SP - 7311

EP - 7314

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Porous organic crystals crosslinked by free-radical reactions

Abstract

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