Photoreductive chlorine elimination from a Ni(iii)Cl2complex supported by a tetradentate pyridinophane ligand

Hanah Na; Michael B. Watson; Fengzhi Tang; Nigam P. Rath; Liviu M. Mirica

doi:10.1039/d1cc02114a

Photoreductive chlorine elimination from a Ni(iii)Cl₂complex supported by a tetradentate pyridinophane ligand

Hanah Na, Michael B. Watson, Fengzhi Tang, Nigam P. Rath, Liviu M. Mirica

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Abstract

Herein we report the isolation, characterization, and photoreactivity of a stable Ni^IIIdichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state.

Original language	English
Pages (from-to)	7264-7267
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	59
DOIs	https://doi.org/10.1039/d1cc02114a
State	Published - Jul 28 2021

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title = "Photoreductive chlorine elimination from a Ni(iii)Cl2complex supported by a tetradentate pyridinophane ligand",

abstract = "Herein we report the isolation, characterization, and photoreactivity of a stable NiIIIdichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state.",

author = "Hanah Na and Watson, {Michael B.} and Fengzhi Tang and Rath, {Nigam P.} and Mirica, {Liviu M.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

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T1 - Photoreductive chlorine elimination from a Ni(iii)Cl2complex supported by a tetradentate pyridinophane ligand

AU - Na, Hanah

AU - Watson, Michael B.

AU - Tang, Fengzhi

AU - Rath, Nigam P.

AU - Mirica, Liviu M.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/7/28

Y1 - 2021/7/28

N2 - Herein we report the isolation, characterization, and photoreactivity of a stable NiIIIdichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state.

AB - Herein we report the isolation, characterization, and photoreactivity of a stable NiIIIdichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state.

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U2 - 10.1039/d1cc02114a

DO - 10.1039/d1cc02114a

M3 - Article

C2 - 34195702

AN - SCOPUS:85111074544

SN - 1359-7345

VL - 57

SP - 7264

EP - 7267

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Photoreductive chlorine elimination from a Ni(iii)Cl₂complex supported by a tetradentate pyridinophane ligand

Abstract

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