Photodissociation Study of C6H6O+· Ions in an Ion Cyclotron Resonance Spectrometer

P. N.T. van Velzen; W. J. van der Hart; J. van der Greef; N. M.M. Nibbering; M. L. Gross

doi:10.1021/ja00369a009

Photodissociation Study of C₆H₆O⁺· Ions in an Ion Cyclotron Resonance Spectrometer

P. N.T. van Velzen, W. J. van der Hart, J. van der Greef, N. M.M. Nibbering, M. L. Gross

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Abstract

Tautomeric phenol and 1,3-cyclohexadien-5-one radical cations exist as distinct, stable species in the gas phase. This is established by a study of the photodissociation spectra of C₆H₆O⁺- ions generated from four sources. Specifically, the ionized phenol and the C₆H₆O⁺· from phenetole exist principally as the phenol structure. On the other hand, C₆H₆O⁺· generated from bicyclo[2.2.2]oct-2-ene-5,7-dione and 2-phenoxyethyl chloride exist as a mixture of keto and enol structures.

Original language	English
Pages (from-to)	1208-1212
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	104
Issue number	5
DOIs	https://doi.org/10.1021/ja00369a009
State	Published - 1982

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@article{c4d29a5ec2b74eb7ba6b225d50f8d8d9,

title = "Photodissociation Study of C6H6O+· Ions in an Ion Cyclotron Resonance Spectrometer",

abstract = "Tautomeric phenol and 1,3-cyclohexadien-5-one radical cations exist as distinct, stable species in the gas phase. This is established by a study of the photodissociation spectra of C6H6O+- ions generated from four sources. Specifically, the ionized phenol and the C6H6O+· from phenetole exist principally as the phenol structure. On the other hand, C6H6O+· generated from bicyclo[2.2.2]oct-2-ene-5,7-dione and 2-phenoxyethyl chloride exist as a mixture of keto and enol structures.",

author = "{van Velzen}, {P. N.T.} and {van der Hart}, {W. J.} and {van der Greef}, J. and Nibbering, {N. M.M.} and Gross, {M. L.}",

year = "1982",

doi = "10.1021/ja00369a009",

language = "English",

volume = "104",

pages = "1208--1212",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - Photodissociation Study of C6H6O+· Ions in an Ion Cyclotron Resonance Spectrometer

AU - van Velzen, P. N.T.

AU - van der Hart, W. J.

AU - van der Greef, J.

AU - Nibbering, N. M.M.

AU - Gross, M. L.

PY - 1982

Y1 - 1982

N2 - Tautomeric phenol and 1,3-cyclohexadien-5-one radical cations exist as distinct, stable species in the gas phase. This is established by a study of the photodissociation spectra of C6H6O+- ions generated from four sources. Specifically, the ionized phenol and the C6H6O+· from phenetole exist principally as the phenol structure. On the other hand, C6H6O+· generated from bicyclo[2.2.2]oct-2-ene-5,7-dione and 2-phenoxyethyl chloride exist as a mixture of keto and enol structures.

AB - Tautomeric phenol and 1,3-cyclohexadien-5-one radical cations exist as distinct, stable species in the gas phase. This is established by a study of the photodissociation spectra of C6H6O+- ions generated from four sources. Specifically, the ionized phenol and the C6H6O+· from phenetole exist principally as the phenol structure. On the other hand, C6H6O+· generated from bicyclo[2.2.2]oct-2-ene-5,7-dione and 2-phenoxyethyl chloride exist as a mixture of keto and enol structures.

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U2 - 10.1021/ja00369a009

DO - 10.1021/ja00369a009

M3 - Article

AN - SCOPUS:33845554101

SN - 0002-7863

VL - 104

SP - 1208

EP - 1212

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Photodissociation Study of C₆H₆O⁺· Ions in an Ion Cyclotron Resonance Spectrometer

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