Photochemistry of Cobalt Carbonyl Complexes Having a Cobalt-Silicon Bond and its Importance in Activation of Catalysis

Carol L. Reichel; Mark S. Wrighton

doi:10.1021/ic50214a058

Photochemistry of Cobalt Carbonyl Complexes Having a Cobalt-Silicon Bond and its Importance in Activation of Catalysis

Carol L. Reichel
, Mark S. Wrighton

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

We wish to report results of experiments that establish the relative importance of photochemical cleavage of the Co-Si bond vs. the dissociative loss of CO in R₃SiCo(CO)₄ (eq 1 vs. eq 2).

Original language	English
Pages (from-to)	3858-3860
Number of pages	3
Journal	Inorganic Chemistry
Volume	19
Issue number	12
DOIs	https://doi.org/10.1021/ic50214a058
State	Published - 1980

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title = "Photochemistry of Cobalt Carbonyl Complexes Having a Cobalt-Silicon Bond and its Importance in Activation of Catalysis",

abstract = "We wish to report results of experiments that establish the relative importance of photochemical cleavage of the Co-Si bond vs. the dissociative loss of CO in R3SiCo(CO)4 (eq 1 vs. eq 2).",

author = "Reichel, \{Carol L.\} and Wrighton, \{Mark S.\}",

year = "1980",

doi = "10.1021/ic50214a058",

language = "English",

volume = "19",

pages = "3858--3860",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "12",

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T1 - Photochemistry of Cobalt Carbonyl Complexes Having a Cobalt-Silicon Bond and its Importance in Activation of Catalysis

AU - Reichel, Carol L.

AU - Wrighton, Mark S.

PY - 1980

Y1 - 1980

N2 - We wish to report results of experiments that establish the relative importance of photochemical cleavage of the Co-Si bond vs. the dissociative loss of CO in R3SiCo(CO)4 (eq 1 vs. eq 2).

AB - We wish to report results of experiments that establish the relative importance of photochemical cleavage of the Co-Si bond vs. the dissociative loss of CO in R3SiCo(CO)4 (eq 1 vs. eq 2).

UR - https://www.scopus.com/pages/publications/33847087799

U2 - 10.1021/ic50214a058

DO - 10.1021/ic50214a058

M3 - Article

AN - SCOPUS:33847087799

SN - 0020-1669

VL - 19

SP - 3858

EP - 3860

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Photochemistry of Cobalt Carbonyl Complexes Having a Cobalt-Silicon Bond and its Importance in Activation of Catalysis

Abstract

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