Photochemical Reactivity of trans-Diacidotetracyanocobaltate(III) Complexes

Mark Wrighton; Harry B. Gray; Vincent Miskowsk; George S. Hammond

doi:10.1021/ic50122a006

Photochemical Reactivity of trans-Diacidotetracyanocobaltate(III) Complexes

Mark Wrighton
, Harry B. Gray
, Vincent Miskowsk
, George S. Hammond

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The photochemistry of trans-Co(CN)₄(SO₃)(X)^n- (X= SO₃^2-, OH^-, or OH₂) is reported. The principal pfeotoreactions involve substitution of the sulfito group yielding aquation products. Photoreduction to yield Co(II) is a minor reaction. Disappearance quantum yields are in the range 0.1-0.6 and are modestly affected by variation in the wavelength of the exciting light.

Original language	English
Pages (from-to)	740-743
Number of pages	4
Journal	Inorganic Chemistry
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/ic50122a006
State	Published - Apr 1 1973

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title = "Photochemical Reactivity of trans-Diacidotetracyanocobaltate(III) Complexes",

abstract = "The photochemistry of trans-Co(CN)4(SO3)(X)n- (X= SO32-, OH-, or OH2) is reported. The principal pfeotoreactions involve substitution of the sulfito group yielding aquation products. Photoreduction to yield Co(II) is a minor reaction. Disappearance quantum yields are in the range 0.1-0.6 and are modestly affected by variation in the wavelength of the exciting light.",

author = "Mark Wrighton and Gray, \{Harry B.\} and Vincent Miskowsk and Hammond, \{George S.\}",

year = "1973",

month = apr,

day = "1",

doi = "10.1021/ic50122a006",

language = "English",

volume = "12",

pages = "740--743",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "4",

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TY - JOUR

T1 - Photochemical Reactivity of trans-Diacidotetracyanocobaltate(III) Complexes

AU - Wrighton, Mark

AU - Gray, Harry B.

AU - Miskowsk, Vincent

AU - Hammond, George S.

PY - 1973/4/1

Y1 - 1973/4/1

N2 - The photochemistry of trans-Co(CN)4(SO3)(X)n- (X= SO32-, OH-, or OH2) is reported. The principal pfeotoreactions involve substitution of the sulfito group yielding aquation products. Photoreduction to yield Co(II) is a minor reaction. Disappearance quantum yields are in the range 0.1-0.6 and are modestly affected by variation in the wavelength of the exciting light.

AB - The photochemistry of trans-Co(CN)4(SO3)(X)n- (X= SO32-, OH-, or OH2) is reported. The principal pfeotoreactions involve substitution of the sulfito group yielding aquation products. Photoreduction to yield Co(II) is a minor reaction. Disappearance quantum yields are in the range 0.1-0.6 and are modestly affected by variation in the wavelength of the exciting light.

UR - https://www.scopus.com/pages/publications/33947085904

U2 - 10.1021/ic50122a006

DO - 10.1021/ic50122a006

M3 - Article

AN - SCOPUS:33947085904

SN - 0020-1669

VL - 12

SP - 740

EP - 743

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Photochemical Reactivity of trans-Diacidotetracyanocobaltate(III) Complexes

Abstract

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