Oxidative cleavage of oximes with silica-gel-supported chromic acid in nonaqueous media

Mohammed Hashmat Ali; Stacie Greene; Candace J. Wiggin; Saira Khan

doi:10.1080/00397910600616966

Oxidative cleavage of oximes with silica-gel-supported chromic acid in nonaqueous media

Mohammed Hashmat Ali, Stacie Greene, Candace J. Wiggin, Saira Khan

Division of Public Health Sciences

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A simple procedure for a clean and high-yielding oxidative deoximation of benzaldoximes and ketoximes using a silica-gel-supported chromic acid reagent has been developed. This solid-supported reagent allows us to carry out this reaction in nonaqueous dichloromethane reaction media.

Original language	English
Pages (from-to)	1761-1767
Number of pages	7
Journal	Synthetic Communications
Volume	36
Issue number	12
DOIs	https://doi.org/10.1080/00397910600616966
State	Published - 2006

Keywords

Chromic acid
Chromic acid-SiO
Deoximation
Solid support

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10.1080/00397910600616966

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abstract = "A simple procedure for a clean and high-yielding oxidative deoximation of benzaldoximes and ketoximes using a silica-gel-supported chromic acid reagent has been developed. This solid-supported reagent allows us to carry out this reaction in nonaqueous dichloromethane reaction media.",

keywords = "Chromic acid, Chromic acid-SiO, Deoximation, Solid support",

author = "Ali, {Mohammed Hashmat} and Stacie Greene and Wiggin, {Candace J.} and Saira Khan",

note = "Funding Information: We thank the Graduate Research and Funding Committee (GRFC) for financial support. M. H. A. expresses gratitude to Bjorn Olesen for help during the preparation of this manuscript.",

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AU - Ali, Mohammed Hashmat

AU - Greene, Stacie

AU - Wiggin, Candace J.

AU - Khan, Saira

N1 - Funding Information: We thank the Graduate Research and Funding Committee (GRFC) for financial support. M. H. A. expresses gratitude to Bjorn Olesen for help during the preparation of this manuscript.

PY - 2006

Y1 - 2006

N2 - A simple procedure for a clean and high-yielding oxidative deoximation of benzaldoximes and ketoximes using a silica-gel-supported chromic acid reagent has been developed. This solid-supported reagent allows us to carry out this reaction in nonaqueous dichloromethane reaction media.

AB - A simple procedure for a clean and high-yielding oxidative deoximation of benzaldoximes and ketoximes using a silica-gel-supported chromic acid reagent has been developed. This solid-supported reagent allows us to carry out this reaction in nonaqueous dichloromethane reaction media.

KW - Chromic acid

KW - Chromic acid-SiO

KW - Deoximation

KW - Solid support

UR - http://www.scopus.com/inward/record.url?scp=33646781924&partnerID=8YFLogxK

U2 - 10.1080/00397910600616966

DO - 10.1080/00397910600616966

M3 - Article

AN - SCOPUS:33646781924

SN - 0039-7911

VL - 36

SP - 1761

EP - 1767

JO - Synthetic Communications

JF - Synthetic Communications

IS - 12

ER -

Oxidative cleavage of oximes with silica-gel-supported chromic acid in nonaqueous media

Abstract

Keywords

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