Oxapentadienyl-rhodium-phosphine chemistry

John R. Bleeke; Edward Donnay; Nigam P. Rath

doi:10.1021/om020429u

Oxapentadienyl-rhodium-phosphine chemistry

John R. Bleeke
, Edward Donnay
, Nigam P. Rath

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The synthesis of (oxapentadienyl)rhodium complexes was presented. The resulting complexes were 16e species in which the oxapentadienyl ligands were coordinated in an η³-allyl fashion to the rhodium centers. The reactivity of the electron-rich complexes toward simple nucleophiles and electrophiles was explored. X-ray crystal structures of representative complexes were obtained, and a variety of dynamic processes were probed by variable-temperature nuclear magnetic resonance (NMR).

Original language	English
Pages (from-to)	4099-4112
Number of pages	14
Journal	Organometallics
Volume	21
Issue number	20
DOIs	https://doi.org/10.1021/om020429u
State	Published - Sep 30 2002

Access to Document

10.1021/om020429u

Cite this

@article{58f2613b30f24ffa8598dd5d0db909c3,

title = "Oxapentadienyl-rhodium-phosphine chemistry",

abstract = "The synthesis of (oxapentadienyl)rhodium complexes was presented. The resulting complexes were 16e species in which the oxapentadienyl ligands were coordinated in an η3-allyl fashion to the rhodium centers. The reactivity of the electron-rich complexes toward simple nucleophiles and electrophiles was explored. X-ray crystal structures of representative complexes were obtained, and a variety of dynamic processes were probed by variable-temperature nuclear magnetic resonance (NMR).",

author = "Bleeke, \{John R.\} and Edward Donnay and Rath, \{Nigam P.\}",

year = "2002",

month = sep,

day = "30",

doi = "10.1021/om020429u",

language = "English",

volume = "21",

pages = "4099--4112",

journal = "Organometallics",

issn = "0276-7333",

number = "20",

}

TY - JOUR

T1 - Oxapentadienyl-rhodium-phosphine chemistry

AU - Bleeke, John R.

AU - Donnay, Edward

AU - Rath, Nigam P.

PY - 2002/9/30

Y1 - 2002/9/30

N2 - The synthesis of (oxapentadienyl)rhodium complexes was presented. The resulting complexes were 16e species in which the oxapentadienyl ligands were coordinated in an η3-allyl fashion to the rhodium centers. The reactivity of the electron-rich complexes toward simple nucleophiles and electrophiles was explored. X-ray crystal structures of representative complexes were obtained, and a variety of dynamic processes were probed by variable-temperature nuclear magnetic resonance (NMR).

AB - The synthesis of (oxapentadienyl)rhodium complexes was presented. The resulting complexes were 16e species in which the oxapentadienyl ligands were coordinated in an η3-allyl fashion to the rhodium centers. The reactivity of the electron-rich complexes toward simple nucleophiles and electrophiles was explored. X-ray crystal structures of representative complexes were obtained, and a variety of dynamic processes were probed by variable-temperature nuclear magnetic resonance (NMR).

UR - https://www.scopus.com/pages/publications/0037772424

U2 - 10.1021/om020429u

DO - 10.1021/om020429u

M3 - Article

AN - SCOPUS:0037772424

SN - 0276-7333

VL - 21

SP - 4099

EP - 4112

JO - Organometallics

JF - Organometallics

IS - 20

ER -

Oxapentadienyl-rhodium-phosphine chemistry

Abstract

Access to Document

Other files and links

Fingerprint

Cite this