Origin of enantioselectivity in CF3-PIP-catalyzed kinetic resolution of secondary benzylic alcohols

Ximin Li; Peng Liu; K. N. Houk; Vladimir B. Birman

doi:10.1021/ja805275s

Origin of enantioselectivity in CF₃-PIP-catalyzed kinetic resolution of secondary benzylic alcohols

Ximin Li, Peng Liu, K. N. Houk, Vladimir B. Birman

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Computational studies provide support for the involvement of intermolecular π-interactions in the chiral recognition of secondary benzylic alcohols by the enantioselective acyl transfer catalyst CF₃-PIP.

Original language	English
Pages (from-to)	13836-13837
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	42
DOIs	https://doi.org/10.1021/ja805275s
State	Published - Oct 22 2008

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title = "Origin of enantioselectivity in CF3-PIP-catalyzed kinetic resolution of secondary benzylic alcohols",

abstract = "Computational studies provide support for the involvement of intermolecular π-interactions in the chiral recognition of secondary benzylic alcohols by the enantioselective acyl transfer catalyst CF3-PIP.",

author = "Ximin Li and Peng Liu and Houk, \{K. N.\} and Birman, \{Vladimir B.\}",

year = "2008",

month = oct,

day = "22",

doi = "10.1021/ja805275s",

language = "English",

volume = "130",

pages = "13836--13837",

journal = "Journal of the American Chemical Society",

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T1 - Origin of enantioselectivity in CF3-PIP-catalyzed kinetic resolution of secondary benzylic alcohols

AU - Li, Ximin

AU - Liu, Peng

AU - Houk, K. N.

AU - Birman, Vladimir B.

PY - 2008/10/22

Y1 - 2008/10/22

N2 - Computational studies provide support for the involvement of intermolecular π-interactions in the chiral recognition of secondary benzylic alcohols by the enantioselective acyl transfer catalyst CF3-PIP.

AB - Computational studies provide support for the involvement of intermolecular π-interactions in the chiral recognition of secondary benzylic alcohols by the enantioselective acyl transfer catalyst CF3-PIP.

UR - https://www.scopus.com/pages/publications/54249095628

U2 - 10.1021/ja805275s

DO - 10.1021/ja805275s

M3 - Article

C2 - 18817392

AN - SCOPUS:54249095628

SN - 0002-7863

VL - 130

SP - 13836

EP - 13837

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 42

ER -

Origin of enantioselectivity in CF₃-PIP-catalyzed kinetic resolution of secondary benzylic alcohols

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