Noble gas composition, cosmic-ray exposure age, ³⁹Ar-⁴⁰Ar, and I-Xe analyses of ungrouped achondrite NWA 7325

Northwest Africa (NWA) 7325 is an anomalous achondrite that experienced episodes of large-degree melt extraction and interaction with melt under reducing conditions. Its composition led to speculations about a Mercurian origin and provoked a series of studies of this meteorite. We present the noble gas composition, and results of ⁴⁰Ar/³⁹Ar and ¹²⁹I-¹²⁹Xe studies of whole rock splits of NWA 7325. The light noble gases are dominated by cosmogenic isotopes. ²¹Ne and ³⁸Ar cosmic-ray exposure ages are 25.6 and 18.9 Ma, respectively, when calculated with a nominal whole rock composition. This ³⁸Ar age is in reasonable agreement with a cosmic-ray exposure age of 17.5 Ma derived in our ⁴⁰Ar/³⁹Ar dating study. Due to the low K-content of 19 ± 1 ppm and high Ca-content of approximately 12.40 ± 0.15 wt%, no reliable ⁴⁰Ar/³⁹Ar age could be determined. The integrated age strongly depends on the choice of an initial ⁴⁰Ar/³⁶Ar ratio. An air-like component is dominant in lower temperature extractions and assuming air ⁴⁰Ar/³⁶Ar for the trapped component results in a calculated integrated age of 3200 ± 260 (1σ) Ma. This may represent the upper age limit for a major reheating event affecting the K-Ar system. Results of ¹²⁹I-¹²⁹Xe dating give no useful chronological information, i.e., no isochron is observed. Considering the highest ¹²⁹Xe*/¹²⁸Xe_I ratio as equivalent to a lower age limit, we calculate an I-Xe age of about 4536 Ma. In addition, elevated ¹²⁹Xe/¹³²Xe ratios of up to 1.65 ± 0.18 in higher temperature extractions indicate an early formation of NWA 7325, with subsequent disturbance of the I-Xe system.