Mean vibrational amplitudes of the (O...O) and (S...S) distances for carbon suboxide and carbon subsulfide

Wm Hayden Smith

doi:10.1016/0009-2614(69)80158-2

Mean vibrational amplitudes of the (O...O) and (S...S) distances for carbon suboxide and carbon subsulfide

Wm Hayden Smith

Department of Earth & Planetary Sciences

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The observed mean amplitude of vibration for the (O...O) distance of carbon suboxide is not in agreement with the usual harmonic approximation calculation. The discrepancy can be understood and approximately calculated using a simple model for interaction with the central carbon bending motion. A similar result is predicted for C₃S₂.

Original language	English
Pages (from-to)	430-432
Number of pages	3
Journal	Chemical Physics Letters
Volume	3
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(69)80158-2
State	Published - Jun 1969

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title = "Mean vibrational amplitudes of the (O...O) and (S...S) distances for carbon suboxide and carbon subsulfide",

abstract = "The observed mean amplitude of vibration for the (O...O) distance of carbon suboxide is not in agreement with the usual harmonic approximation calculation. The discrepancy can be understood and approximately calculated using a simple model for interaction with the central carbon bending motion. A similar result is predicted for C3S2.",

author = "\{Hayden Smith\}, Wm",

year = "1969",

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T1 - Mean vibrational amplitudes of the (O...O) and (S...S) distances for carbon suboxide and carbon subsulfide

AU - Hayden Smith, Wm

PY - 1969/6

Y1 - 1969/6

N2 - The observed mean amplitude of vibration for the (O...O) distance of carbon suboxide is not in agreement with the usual harmonic approximation calculation. The discrepancy can be understood and approximately calculated using a simple model for interaction with the central carbon bending motion. A similar result is predicted for C3S2.

AB - The observed mean amplitude of vibration for the (O...O) distance of carbon suboxide is not in agreement with the usual harmonic approximation calculation. The discrepancy can be understood and approximately calculated using a simple model for interaction with the central carbon bending motion. A similar result is predicted for C3S2.

UR - https://www.scopus.com/pages/publications/49849119389

U2 - 10.1016/0009-2614(69)80158-2

DO - 10.1016/0009-2614(69)80158-2

M3 - Article

AN - SCOPUS:49849119389

SN - 0009-2614

VL - 3

SP - 430

EP - 432

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Mean vibrational amplitudes of the (O...O) and (S...S) distances for carbon suboxide and carbon subsulfide

Abstract

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