Manganese-Centered Coupling of Pentadlenyl Llgands. Isolation of a Metal Complex of the Coupled Product

John R. Bleeke; John J. Kotyk

doi:10.1021/om50003a040

Manganese-Centered Coupling of Pentadlenyl Llgands. Isolation of a Metal Complex of the Coupled Product

John R. Bleeke
, John J. Kotyk

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Reaction of MnBr₂ with potassium 2,4-di-methyipentadienide and P(CH₃)₃ results in the formation of (η⁸-2,4,7,9-tetramethyl-1,3I7,9-decatetraene)(tri-methylphosphine)manganese (1). The decatetraene ligand is derived from the manganese-centered coupling of two 2,4-dimethylpentadienyl ligands. The crystal structure of 1, as determined by a single-crystal X-ray diffraction study, is reported. A mechanism for the pentadienyl coupling reaction is proposed.

Original language	English
Pages (from-to)	1263-1265
Number of pages	3
Journal	Organometallics
Volume	2
Issue number	9
DOIs	https://doi.org/10.1021/om50003a040
State	Published - Sep 1983

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title = "Manganese-Centered Coupling of Pentadlenyl Llgands. Isolation of a Metal Complex of the Coupled Product",

abstract = "Reaction of MnBr2 with potassium 2,4-di-methyipentadienide and P(CH3)3 results in the formation of (η8-2,4,7,9-tetramethyl-1,3I7,9-decatetraene)(tri-methylphosphine)manganese (1). The decatetraene ligand is derived from the manganese-centered coupling of two 2,4-dimethylpentadienyl ligands. The crystal structure of 1, as determined by a single-crystal X-ray diffraction study, is reported. A mechanism for the pentadienyl coupling reaction is proposed.",

author = "Bleeke, \{John R.\} and Kotyk, \{John J.\}",

year = "1983",

month = sep,

doi = "10.1021/om50003a040",

language = "English",

volume = "2",

pages = "1263--1265",

journal = "Organometallics",

issn = "0276-7333",

number = "9",

}

TY - JOUR

T1 - Manganese-Centered Coupling of Pentadlenyl Llgands. Isolation of a Metal Complex of the Coupled Product

AU - Bleeke, John R.

AU - Kotyk, John J.

PY - 1983/9

Y1 - 1983/9

N2 - Reaction of MnBr2 with potassium 2,4-di-methyipentadienide and P(CH3)3 results in the formation of (η8-2,4,7,9-tetramethyl-1,3I7,9-decatetraene)(tri-methylphosphine)manganese (1). The decatetraene ligand is derived from the manganese-centered coupling of two 2,4-dimethylpentadienyl ligands. The crystal structure of 1, as determined by a single-crystal X-ray diffraction study, is reported. A mechanism for the pentadienyl coupling reaction is proposed.

AB - Reaction of MnBr2 with potassium 2,4-di-methyipentadienide and P(CH3)3 results in the formation of (η8-2,4,7,9-tetramethyl-1,3I7,9-decatetraene)(tri-methylphosphine)manganese (1). The decatetraene ligand is derived from the manganese-centered coupling of two 2,4-dimethylpentadienyl ligands. The crystal structure of 1, as determined by a single-crystal X-ray diffraction study, is reported. A mechanism for the pentadienyl coupling reaction is proposed.

UR - https://www.scopus.com/pages/publications/9744230372

U2 - 10.1021/om50003a040

DO - 10.1021/om50003a040

M3 - Article

AN - SCOPUS:9744230372

SN - 0276-7333

VL - 2

SP - 1263

EP - 1265

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Manganese-Centered Coupling of Pentadlenyl Llgands. Isolation of a Metal Complex of the Coupled Product

Abstract

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