Local structure in hydrogenated Ti-Zr-Ni quasicrystals and approximants

A. Sadoc; E. H. Majzoub; V. T. Huett; K. F. Kelton

doi:10.1016/S0925-8388(02)01218-5

Local structure in hydrogenated Ti-Zr-Ni quasicrystals and approximants

A. Sadoc
, E. H. Majzoub
, V. T. Huett
, K. F. Kelton

Department of Physics

Research output: Contribution to journal › Conference article › peer-review

18 Scopus citations

Abstract

We have investigated the influence of hydrogen on the local structure of Ti-Zr-Ni alloys, icosahedral quasicrystals or crystalline approximants, using extended X-ray absorption fine structure (EXAFS). With an increasing hydrogen-to-metal ratio from 0 to 1.7, a general increase of all the mean first distances was found except for the Zr-Ni (Ni-Zr) ones. The perturbation of the (quasi)lattice, induced by hydrogenation, is a maximum around the Ti and Zr atoms, which suggests that hydrogen atoms sit preferentially near titanium and zirconium atoms.

Original language	English
Pages (from-to)	96-99
Number of pages	4
Journal	Journal of Alloys and Compounds
Volume	356-357
DOIs	https://doi.org/10.1016/S0925-8388(02)01218-5
State	Published - Aug 11 2003
Event	Proceedings of the Eight International Symposium on Metal Hyd (MH 2002) - Annecy, France Duration: Sep 2 2002 → Sep 6 2002

Keywords

EXAFS
Hydrogen storage materials
Liquid quenching
Synchrotron radiation
X-Ray spectroscopies

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10.1016/S0925-8388(02)01218-5

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title = "Local structure in hydrogenated Ti-Zr-Ni quasicrystals and approximants",

abstract = "We have investigated the influence of hydrogen on the local structure of Ti-Zr-Ni alloys, icosahedral quasicrystals or crystalline approximants, using extended X-ray absorption fine structure (EXAFS). With an increasing hydrogen-to-metal ratio from 0 to 1.7, a general increase of all the mean first distances was found except for the Zr-Ni (Ni-Zr) ones. The perturbation of the (quasi)lattice, induced by hydrogenation, is a maximum around the Ti and Zr atoms, which suggests that hydrogen atoms sit preferentially near titanium and zirconium atoms.",

keywords = "EXAFS, Hydrogen storage materials, Liquid quenching, Synchrotron radiation, X-Ray spectroscopies",

author = "A. Sadoc and Majzoub, \{E. H.\} and Huett, \{V. T.\} and Kelton, \{K. F.\}",

year = "2003",

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day = "11",

doi = "10.1016/S0925-8388(02)01218-5",

language = "English",

volume = "356-357",

pages = "96--99",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

note = "Proceedings of the Eight International Symposium on Metal Hyd (MH 2002) ; Conference date: 02-09-2002 Through 06-09-2002",

}

TY - JOUR

T1 - Local structure in hydrogenated Ti-Zr-Ni quasicrystals and approximants

AU - Sadoc, A.

AU - Majzoub, E. H.

AU - Huett, V. T.

AU - Kelton, K. F.

PY - 2003/8/11

Y1 - 2003/8/11

N2 - We have investigated the influence of hydrogen on the local structure of Ti-Zr-Ni alloys, icosahedral quasicrystals or crystalline approximants, using extended X-ray absorption fine structure (EXAFS). With an increasing hydrogen-to-metal ratio from 0 to 1.7, a general increase of all the mean first distances was found except for the Zr-Ni (Ni-Zr) ones. The perturbation of the (quasi)lattice, induced by hydrogenation, is a maximum around the Ti and Zr atoms, which suggests that hydrogen atoms sit preferentially near titanium and zirconium atoms.

AB - We have investigated the influence of hydrogen on the local structure of Ti-Zr-Ni alloys, icosahedral quasicrystals or crystalline approximants, using extended X-ray absorption fine structure (EXAFS). With an increasing hydrogen-to-metal ratio from 0 to 1.7, a general increase of all the mean first distances was found except for the Zr-Ni (Ni-Zr) ones. The perturbation of the (quasi)lattice, induced by hydrogenation, is a maximum around the Ti and Zr atoms, which suggests that hydrogen atoms sit preferentially near titanium and zirconium atoms.

KW - EXAFS

KW - Hydrogen storage materials

KW - Liquid quenching

KW - Synchrotron radiation

KW - X-Ray spectroscopies

UR - https://www.scopus.com/pages/publications/0042197458

U2 - 10.1016/S0925-8388(02)01218-5

DO - 10.1016/S0925-8388(02)01218-5

M3 - Conference article

AN - SCOPUS:0042197458

SN - 0925-8388

VL - 356-357

SP - 96

EP - 99

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

T2 - Proceedings of the Eight International Symposium on Metal Hyd (MH 2002)

Y2 - 2 September 2002 through 6 September 2002

ER -

Local structure in hydrogenated Ti-Zr-Ni quasicrystals and approximants

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Keywords

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