Lattice models of ionic systems with charge asymmetry

Maxim N. Artyomov; Vladimir Kobelev; Anatoly B. Kolomeisky

doi:10.1063/1.1558311

Lattice models of ionic systems with charge asymmetry

Maxim N. Artyomov, Vladimir Kobelev, Anatoly B. Kolomeisky

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Abstract

A thermodynamic investigation of charge-asymmetric lattice models of electrolytes is presented. By explicitly including the clustering of oppositely charged particles and ion-cluster interactions, phase diagrams for 2:1 and 3:1 lattice electrolytes are obtained, and the critical point for the 4:1 ionic system is located. Thus, the results accord well with the trend obtained in recent Monte Carlo simulations and the continuum DHBjCI theory.

Original language	English
Pages (from-to)	6394-6402
Number of pages	9
Journal	Journal of Chemical Physics
Volume	118
Issue number	14
DOIs	https://doi.org/10.1063/1.1558311
State	Published - Apr 8 2003

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title = "Lattice models of ionic systems with charge asymmetry",

abstract = "A thermodynamic investigation of charge-asymmetric lattice models of electrolytes is presented. By explicitly including the clustering of oppositely charged particles and ion-cluster interactions, phase diagrams for 2:1 and 3:1 lattice electrolytes are obtained, and the critical point for the 4:1 ionic system is located. Thus, the results accord well with the trend obtained in recent Monte Carlo simulations and the continuum DHBjCI theory.",

author = "Artyomov, {Maxim N.} and Vladimir Kobelev and Kolomeisky, {Anatoly B.}",

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AU - Artyomov, Maxim N.

AU - Kobelev, Vladimir

AU - Kolomeisky, Anatoly B.

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Y1 - 2003/4/8

N2 - A thermodynamic investigation of charge-asymmetric lattice models of electrolytes is presented. By explicitly including the clustering of oppositely charged particles and ion-cluster interactions, phase diagrams for 2:1 and 3:1 lattice electrolytes are obtained, and the critical point for the 4:1 ionic system is located. Thus, the results accord well with the trend obtained in recent Monte Carlo simulations and the continuum DHBjCI theory.

AB - A thermodynamic investigation of charge-asymmetric lattice models of electrolytes is presented. By explicitly including the clustering of oppositely charged particles and ion-cluster interactions, phase diagrams for 2:1 and 3:1 lattice electrolytes are obtained, and the critical point for the 4:1 ionic system is located. Thus, the results accord well with the trend obtained in recent Monte Carlo simulations and the continuum DHBjCI theory.

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U2 - 10.1063/1.1558311

DO - 10.1063/1.1558311

M3 - Article

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SN - 0021-9606

VL - 118

SP - 6394

EP - 6402

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 14

ER -

Lattice models of ionic systems with charge asymmetry

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