Kinetics of epoxidation of propylene over TS-1 in isopropanol

Xinhua Liang; Zhentao Mi; Yulong Wu; Li Wang; Enhui Xing

doi:10.1023/B:REAC.0000006127.34574.a7

Kinetics of epoxidation of propylene over TS-1 in isopropanol

Xinhua Liang
, Zhentao Mi
, Yulong Wu
, Li Wang
, Enhui Xing

Department of Energy, Environmental & Chemical Engineering

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The intrinsic kinetics of propylene epoxidation with H₂O ₂ catalyzed by TS-1 in isopropanol/water system was investigated. A kinetic model was established in accordance with the proposed reaction mechanism. Based on the experimental data, parameters were estimated, indicating that the Eley-Rideal model fits precisely the experimental data.

Original language	English
Pages (from-to)	207-215
Number of pages	9
Journal	Reaction Kinetics and Catalysis Letters
Volume	80
Issue number	2
DOIs	https://doi.org/10.1023/B:REAC.0000006127.34574.a7
State	Published - 2003

Keywords

Intrinsic kinetics
Isopropanol
PO (propylene oxide)
Titanium Silicalite (TS-1)

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10.1023/B:REAC.0000006127.34574.a7

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title = "Kinetics of epoxidation of propylene over TS-1 in isopropanol",

abstract = "The intrinsic kinetics of propylene epoxidation with H2O 2 catalyzed by TS-1 in isopropanol/water system was investigated. A kinetic model was established in accordance with the proposed reaction mechanism. Based on the experimental data, parameters were estimated, indicating that the Eley-Rideal model fits precisely the experimental data.",

keywords = "Intrinsic kinetics, Isopropanol, PO (propylene oxide), Titanium Silicalite (TS-1)",

author = "Xinhua Liang and Zhentao Mi and Yulong Wu and Li Wang and Enhui Xing",

year = "2003",

doi = "10.1023/B:REAC.0000006127.34574.a7",

language = "English",

volume = "80",

pages = "207--215",

journal = "Reaction Kinetics and Catalysis Letters",

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TY - JOUR

T1 - Kinetics of epoxidation of propylene over TS-1 in isopropanol

AU - Liang, Xinhua

AU - Mi, Zhentao

AU - Wu, Yulong

AU - Wang, Li

AU - Xing, Enhui

PY - 2003

Y1 - 2003

N2 - The intrinsic kinetics of propylene epoxidation with H2O 2 catalyzed by TS-1 in isopropanol/water system was investigated. A kinetic model was established in accordance with the proposed reaction mechanism. Based on the experimental data, parameters were estimated, indicating that the Eley-Rideal model fits precisely the experimental data.

AB - The intrinsic kinetics of propylene epoxidation with H2O 2 catalyzed by TS-1 in isopropanol/water system was investigated. A kinetic model was established in accordance with the proposed reaction mechanism. Based on the experimental data, parameters were estimated, indicating that the Eley-Rideal model fits precisely the experimental data.

KW - Intrinsic kinetics

KW - Isopropanol

KW - PO (propylene oxide)

KW - Titanium Silicalite (TS-1)

UR - https://www.scopus.com/pages/publications/0344704242

U2 - 10.1023/B:REAC.0000006127.34574.a7

DO - 10.1023/B:REAC.0000006127.34574.a7

M3 - Article

AN - SCOPUS:0344704242

SN - 0133-1736

VL - 80

SP - 207

EP - 215

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

Kinetics of epoxidation of propylene over TS-1 in isopropanol

Abstract

Keywords

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