Kinetic resolution of alcohols using a 1,2-dihydroimidazo[1,2-a]quinoline enantioselective acylation catalyst

Vladimir B. Birman; Hui Jiang

doi:10.1021/ol051063v

Kinetic resolution of alcohols using a 1,2-dihydroimidazo[1,2-a]quinoline enantioselective acylation catalyst

Vladimir B. Birman
, Hui Jiang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

(Chemical Equation Presented) A new enantioselective acylation catalyst (CI-PIQ), designed to provide enhanced π-stacking with benzylic and cinnamyl alcohol substrates, was found to give considerably increased reaction rates and selectivities compared with the first-generation catalyst CF₃-PIP.

Original language	English
Pages (from-to)	3445-3447
Number of pages	3
Journal	Organic Letters
Volume	7
Issue number	16
DOIs	https://doi.org/10.1021/ol051063v
State	Published - Aug 4 2005

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title = "Kinetic resolution of alcohols using a 1,2-dihydroimidazo[1,2-a]quinoline enantioselective acylation catalyst",

abstract = "(Chemical Equation Presented) A new enantioselective acylation catalyst (CI-PIQ), designed to provide enhanced π-stacking with benzylic and cinnamyl alcohol substrates, was found to give considerably increased reaction rates and selectivities compared with the first-generation catalyst CF3-PIP.",

author = "Birman, \{Vladimir B.\} and Hui Jiang",

year = "2005",

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doi = "10.1021/ol051063v",

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T1 - Kinetic resolution of alcohols using a 1,2-dihydroimidazo[1,2-a]quinoline enantioselective acylation catalyst

AU - Birman, Vladimir B.

AU - Jiang, Hui

PY - 2005/8/4

Y1 - 2005/8/4

N2 - (Chemical Equation Presented) A new enantioselective acylation catalyst (CI-PIQ), designed to provide enhanced π-stacking with benzylic and cinnamyl alcohol substrates, was found to give considerably increased reaction rates and selectivities compared with the first-generation catalyst CF3-PIP.

AB - (Chemical Equation Presented) A new enantioselective acylation catalyst (CI-PIQ), designed to provide enhanced π-stacking with benzylic and cinnamyl alcohol substrates, was found to give considerably increased reaction rates and selectivities compared with the first-generation catalyst CF3-PIP.

UR - https://www.scopus.com/pages/publications/23944460499

U2 - 10.1021/ol051063v

DO - 10.1021/ol051063v

M3 - Article

C2 - 16048313

AN - SCOPUS:23944460499

SN - 1523-7060

VL - 7

SP - 3445

EP - 3447

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Kinetic resolution of alcohols using a 1,2-dihydroimidazo[1,2-a]quinoline enantioselective acylation catalyst

Abstract

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