Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions

Abigail O. Delawder; Mark S. Palmquist; Jovelt M. Dorsainvil; Nathan D. Colley; Tiana M. Saak; Max C. Gruschka; Xuesong Li; Lei Li; Yipei Zhang; Jonathan C. Barnes

doi:10.1039/d1cc06912h

Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions

Abigail O. Delawder
, Mark S. Palmquist
, Jovelt M. Dorsainvil
, Nathan D. Colley
, Tiana M. Saak
, Max C. Gruschka
, Xuesong Li
, Lei Li
, Yipei Zhang
, Jonathan C. Barnes

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported to date. Facile degradation using inorganic and organic aqueous bases was also demonstrated for a representative oligoviologen (6V-Me·12Cl), a polyviologen (26V-Me·52Cl), and oligoviologen-crosslinked hydrogels.

Original language	English
Pages (from-to)	1358-1361
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	9
DOIs	https://doi.org/10.1039/d1cc06912h
State	Published - Jan 28 2022

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title = "Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions",

abstract = "An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported to date. Facile degradation using inorganic and organic aqueous bases was also demonstrated for a representative oligoviologen (6V-Me·12Cl), a polyviologen (26V-Me·52Cl), and oligoviologen-crosslinked hydrogels.",

author = "Delawder, \{Abigail O.\} and Palmquist, \{Mark S.\} and Dorsainvil, \{Jovelt M.\} and Colley, \{Nathan D.\} and Saak, \{Tiana M.\} and Gruschka, \{Max C.\} and Xuesong Li and Lei Li and Yipei Zhang and Barnes, \{Jonathan C.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2022",

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day = "28",

doi = "10.1039/d1cc06912h",

language = "English",

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T1 - Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions

AU - Delawder, Abigail O.

AU - Palmquist, Mark S.

AU - Dorsainvil, Jovelt M.

AU - Colley, Nathan D.

AU - Saak, Tiana M.

AU - Gruschka, Max C.

AU - Li, Xuesong

AU - Li, Lei

AU - Zhang, Yipei

AU - Barnes, Jonathan C.

PY - 2022/1/28

Y1 - 2022/1/28

N2 - An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported to date. Facile degradation using inorganic and organic aqueous bases was also demonstrated for a representative oligoviologen (6V-Me·12Cl), a polyviologen (26V-Me·52Cl), and oligoviologen-crosslinked hydrogels.

AB - An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported to date. Facile degradation using inorganic and organic aqueous bases was also demonstrated for a representative oligoviologen (6V-Me·12Cl), a polyviologen (26V-Me·52Cl), and oligoviologen-crosslinked hydrogels.

UR - https://www.scopus.com/pages/publications/85123901560

U2 - 10.1039/d1cc06912h

DO - 10.1039/d1cc06912h

M3 - Article

C2 - 34989373

AN - SCOPUS:85123901560

SN - 1359-7345

VL - 58

SP - 1358

EP - 1361

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions

Abstract

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