Intra-cluster photoelectron interactions: Scattering and dissociative attachment in halide-methyl halide cluster anions

Richard Mabbs; Matthew Van Duzor; Foster Mbaiwa; Jie Wei

doi:10.1088/1742-6596/194/5/052034

Intra-cluster photoelectron interactions: Scattering and dissociative attachment in halide-methyl halide cluster anions

Richard Mabbs
, Matthew Van Duzor
, Foster Mbaiwa
, Jie Wei

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

I^- and I^-·CH₃I photodetachment over a range of wavelengths generally shows similar spectral features but strikingly different photoelectron angular distributions. The difference in angular distribution is due to intracluster electron scattering. Additionally, within narrow energy ranges, the cluster anion detachment yields new spectral transitions. These correspond to excitation of a vibrational Feshbach resonance and subsequent fragmentation, analogous to a dissociative electron attachment process. Fs time resolved studies of dissociative electron attachment are discussed.

Original language	English
Article number	052034
Journal	Journal of Physics: Conference Series
Volume	194
Issue number	5
DOIs	https://doi.org/10.1088/1742-6596/194/5/052034
State	Published - Dec 24 2009
Event	26th International Conference on Photonic, Electronic and Atomic Collisions - Kalamazoo, United States Duration: Jul 22 2009 → Jul 28 2009

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title = "Intra-cluster photoelectron interactions: Scattering and dissociative attachment in halide-methyl halide cluster anions",

abstract = "I- and I-·CH3I photodetachment over a range of wavelengths generally shows similar spectral features but strikingly different photoelectron angular distributions. The difference in angular distribution is due to intracluster electron scattering. Additionally, within narrow energy ranges, the cluster anion detachment yields new spectral transitions. These correspond to excitation of a vibrational Feshbach resonance and subsequent fragmentation, analogous to a dissociative electron attachment process. Fs time resolved studies of dissociative electron attachment are discussed.",

author = "Richard Mabbs and \{Van Duzor\}, Matthew and Foster Mbaiwa and Jie Wei",

note = "Publisher Copyright: {\textcopyright} 2009 IOP Publishing Ltd.; 26th International Conference on Photonic, Electronic and Atomic Collisions ; Conference date: 22-07-2009 Through 28-07-2009",

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T1 - Intra-cluster photoelectron interactions

T2 - 26th International Conference on Photonic, Electronic and Atomic Collisions

AU - Mabbs, Richard

AU - Van Duzor, Matthew

AU - Mbaiwa, Foster

AU - Wei, Jie

PY - 2009/12/24

Y1 - 2009/12/24

N2 - I- and I-·CH3I photodetachment over a range of wavelengths generally shows similar spectral features but strikingly different photoelectron angular distributions. The difference in angular distribution is due to intracluster electron scattering. Additionally, within narrow energy ranges, the cluster anion detachment yields new spectral transitions. These correspond to excitation of a vibrational Feshbach resonance and subsequent fragmentation, analogous to a dissociative electron attachment process. Fs time resolved studies of dissociative electron attachment are discussed.

AB - I- and I-·CH3I photodetachment over a range of wavelengths generally shows similar spectral features but strikingly different photoelectron angular distributions. The difference in angular distribution is due to intracluster electron scattering. Additionally, within narrow energy ranges, the cluster anion detachment yields new spectral transitions. These correspond to excitation of a vibrational Feshbach resonance and subsequent fragmentation, analogous to a dissociative electron attachment process. Fs time resolved studies of dissociative electron attachment are discussed.

UR - https://www.scopus.com/pages/publications/85034972581

U2 - 10.1088/1742-6596/194/5/052034

DO - 10.1088/1742-6596/194/5/052034

M3 - Conference article

AN - SCOPUS:85034972581

SN - 1742-6588

VL - 194

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

IS - 5

M1 - 052034

Y2 - 22 July 2009 through 28 July 2009

ER -

Intra-cluster photoelectron interactions: Scattering and dissociative attachment in halide-methyl halide cluster anions

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