TY - JOUR
T1 - Insights into the Mechanism of CO2 Electroreduction by Molecular Palladium-Pyridinophane Complexes
AU - Chakrabarti, Sagnik
AU - Woods, Toby J.
AU - Mirica, Liviu M.
N1 - Publisher Copyright:
© 2023 American Chemical Society.
PY - 2023/10/16
Y1 - 2023/10/16
N2 - Herein, we report the synthesis, characterization, and electrocatalytic CO2 reduction activity of a series of Pd(II) complexes supported by tetradentate pyridinophane ligands. In particular, we focus on the electrocatalytic CO2 reduction activity of a Pd(II) complex supported by the mixed hard-soft donor ligand 2,11-dithia[3.3](2,6)pyridinophane (N2S2). We also provide spectroscopic evidence of a CO-induced decomposition pathway for the same catalyst, which provides insights into catalyst poisoning for molecular Pd CO2 reduction electrocatalysts.
AB - Herein, we report the synthesis, characterization, and electrocatalytic CO2 reduction activity of a series of Pd(II) complexes supported by tetradentate pyridinophane ligands. In particular, we focus on the electrocatalytic CO2 reduction activity of a Pd(II) complex supported by the mixed hard-soft donor ligand 2,11-dithia[3.3](2,6)pyridinophane (N2S2). We also provide spectroscopic evidence of a CO-induced decomposition pathway for the same catalyst, which provides insights into catalyst poisoning for molecular Pd CO2 reduction electrocatalysts.
UR - http://www.scopus.com/inward/record.url?scp=85175587282&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.3c02236
DO - 10.1021/acs.inorgchem.3c02236
M3 - Article
C2 - 37787756
AN - SCOPUS:85175587282
SN - 0020-1669
VL - 62
SP - 16801
EP - 16809
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 41
ER -