Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols

Vladimir B. Birman; Ximin Li

doi:10.1021/ol703119n

Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols

Vladimir B. Birman
, Ximin Li

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

190 Scopus citations

Abstract

Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.

Original language	English
Pages (from-to)	1115-1118
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	6
DOIs	https://doi.org/10.1021/ol703119n
State	Published - Mar 20 2008

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10.1021/ol703119n

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title = "Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols",

abstract = "Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.",

author = "Birman, \{Vladimir B.\} and Ximin Li",

year = "2008",

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doi = "10.1021/ol703119n",

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T1 - Homobenzotetramisole

T2 - An effective catalyst for kinetic resolution of aryl-cycloalkanols

AU - Birman, Vladimir B.

AU - Li, Ximin

PY - 2008/3/20

Y1 - 2008/3/20

N2 - Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.

AB - Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.

UR - https://www.scopus.com/pages/publications/45549099652

U2 - 10.1021/ol703119n

DO - 10.1021/ol703119n

M3 - Article

C2 - 18278928

AN - SCOPUS:45549099652

SN - 1523-7060

VL - 10

SP - 1115

EP - 1118

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols

Abstract

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