Ground-state Cr+ ions produced by multiphoton ionization of Cr(CO)6

S. K. Huang; Michael L. Gross

doi:10.1021/j100267a005

Ground-state Cr⁺ ions produced by multiphoton ionization of Cr(CO)₆

S. K. Huang
, Michael L. Gross

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Multiphoton dissociation-ionization (MPD/MPI) of volatile chromium hexacarbonyl at 266 and 353 nm generates a more nearly homogeneous or ground-state population of gas-phase metal ions than does electron ionization (EI). This was demonstrated for Cr⁺ by using Fourier transform mass spectrometry to measure the kinetics for the reaction of Cr⁺ generated by either MPD/MPI or EI with neutral Cr(CO)₆. The kinetics for decay of El-produced Cr⁺ ions are composite whereas the rate of disappearance of MPI-produced ions is noncomposite.

Original language	English
Pages (from-to)	4422-4423
Number of pages	2
Journal	Journal of Physical Chemistry
Volume	89
Issue number	21
DOIs	https://doi.org/10.1021/j100267a005
State	Published - 1985

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title = "Ground-state Cr+ ions produced by multiphoton ionization of Cr(CO)6",

abstract = "Multiphoton dissociation-ionization (MPD/MPI) of volatile chromium hexacarbonyl at 266 and 353 nm generates a more nearly homogeneous or ground-state population of gas-phase metal ions than does electron ionization (EI). This was demonstrated for Cr+ by using Fourier transform mass spectrometry to measure the kinetics for the reaction of Cr+ generated by either MPD/MPI or EI with neutral Cr(CO)6. The kinetics for decay of El-produced Cr+ ions are composite whereas the rate of disappearance of MPI-produced ions is noncomposite.",

author = "Huang, \{S. K.\} and Gross, \{Michael L.\}",

year = "1985",

doi = "10.1021/j100267a005",

language = "English",

volume = "89",

pages = "4422--4423",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

number = "21",

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T1 - Ground-state Cr+ ions produced by multiphoton ionization of Cr(CO)6

AU - Huang, S. K.

AU - Gross, Michael L.

PY - 1985

Y1 - 1985

N2 - Multiphoton dissociation-ionization (MPD/MPI) of volatile chromium hexacarbonyl at 266 and 353 nm generates a more nearly homogeneous or ground-state population of gas-phase metal ions than does electron ionization (EI). This was demonstrated for Cr+ by using Fourier transform mass spectrometry to measure the kinetics for the reaction of Cr+ generated by either MPD/MPI or EI with neutral Cr(CO)6. The kinetics for decay of El-produced Cr+ ions are composite whereas the rate of disappearance of MPI-produced ions is noncomposite.

AB - Multiphoton dissociation-ionization (MPD/MPI) of volatile chromium hexacarbonyl at 266 and 353 nm generates a more nearly homogeneous or ground-state population of gas-phase metal ions than does electron ionization (EI). This was demonstrated for Cr+ by using Fourier transform mass spectrometry to measure the kinetics for the reaction of Cr+ generated by either MPD/MPI or EI with neutral Cr(CO)6. The kinetics for decay of El-produced Cr+ ions are composite whereas the rate of disappearance of MPI-produced ions is noncomposite.

UR - https://www.scopus.com/pages/publications/0011813571

U2 - 10.1021/j100267a005

DO - 10.1021/j100267a005

M3 - Article

AN - SCOPUS:0011813571

SN - 0022-3654

VL - 89

SP - 4422

EP - 4423

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 21

ER -

Ground-state Cr⁺ ions produced by multiphoton ionization of Cr(CO)₆

Abstract

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