Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

Junling Sun; Marco Frasconi; Zhichang Liu; Jonathan C. Barnes; Yuping Wang; Dongyang Chen; Charlotte L. Stern; J. Fraser Stoddart

doi:10.1039/c4cc08053j

Formation of ring-in-ring complexes between crown ethers and rigid TVBox⁸⁺

Junling Sun
, Marco Frasconi
, Zhichang Liu
, Jonathan C. Barnes
, Yuping Wang
, Dongyang Chen
, Charlotte L. Stern
, J. Fraser Stoddart

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A rigid octacationic tetraviologen-based cyclophane, TVBox⁸⁺, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 Å and width of 6.1 Å and is capable of encapsulating either two small π-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50]crown-14.

Original language	English
Pages (from-to)	1432-1435
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	8
DOIs	https://doi.org/10.1039/c4cc08053j
State	Published - Jan 28 2015

Access to Document

10.1039/c4cc08053j

Cite this

@article{e3477fc889394289a7aa632b851dbbf8,

title = "Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+",

abstract = "A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 {\AA} and width of 6.1 {\AA} and is capable of encapsulating either two small π-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50]crown-14.",

author = "Junling Sun and Marco Frasconi and Zhichang Liu and Barnes, \{Jonathan C.\} and Yuping Wang and Dongyang Chen and Stern, \{Charlotte L.\} and \{Fraser Stoddart\}, J.",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = jan,

day = "28",

doi = "10.1039/c4cc08053j",

language = "English",

volume = "51",

pages = "1432--1435",

journal = "Chemical Communications",

issn = "1359-7345",

number = "8",

}

TY - JOUR

T1 - Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

AU - Sun, Junling

AU - Frasconi, Marco

AU - Liu, Zhichang

AU - Barnes, Jonathan C.

AU - Wang, Yuping

AU - Chen, Dongyang

AU - Stern, Charlotte L.

AU - Fraser Stoddart, J.

PY - 2015/1/28

Y1 - 2015/1/28

N2 - A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 Å and width of 6.1 Å and is capable of encapsulating either two small π-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50]crown-14.

AB - A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 Å and width of 6.1 Å and is capable of encapsulating either two small π-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50]crown-14.

UR - https://www.scopus.com/pages/publications/84935146257

U2 - 10.1039/c4cc08053j

DO - 10.1039/c4cc08053j

M3 - Article

AN - SCOPUS:84935146257

SN - 1359-7345

VL - 51

SP - 1432

EP - 1435

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Formation of ring-in-ring complexes between crown ethers and rigid TVBox⁸⁺

Abstract

Access to Document

Other files and links

Fingerprint

Cite this