ESR study of coupled pairs of molecules in copper diethyldithiocarbamate

R. K. Cowsik; G. Rangarajan; R. Srinivasan

doi:10.1016/0009-2614(71)80597-3

ESR study of coupled pairs of molecules in copper diethyldithiocarbamate

R. K. Cowsik
, G. Rangarajan
, R. Srinivasan

Department of Physics

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Single crystal ESR study of copper diethyldithiocarbamate has shown evidence for the presence of coupled pairs of Cu⁺⁺ ions. While the g-values for the triplet state remain the same as for the doublet (uncoupled ions), the hyperfine splitting is halved. The zero field splitting parameter D = 276 × 10^-4 cm^-1. The results have been correlated with crystal structure and susceptibility data.

Original language	English
Pages (from-to)	136-138
Number of pages	3
Journal	Chemical Physics Letters
Volume	8
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(71)80597-3
State	Published - Jan 1971

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@article{66fd280fdfce4896ab54847e795afe8a,

title = "ESR study of coupled pairs of molecules in copper diethyldithiocarbamate",

abstract = "Single crystal ESR study of copper diethyldithiocarbamate has shown evidence for the presence of coupled pairs of Cu++ ions. While the g-values for the triplet state remain the same as for the doublet (uncoupled ions), the hyperfine splitting is halved. The zero field splitting parameter D = 276 {\texttimes} 10-4 cm-1. The results have been correlated with crystal structure and susceptibility data.",

author = "Cowsik, \{R. K.\} and G. Rangarajan and R. Srinivasan",

year = "1971",

month = jan,

doi = "10.1016/0009-2614(71)80597-3",

language = "English",

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pages = "136--138",

journal = "Chemical Physics Letters",

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T1 - ESR study of coupled pairs of molecules in copper diethyldithiocarbamate

AU - Cowsik, R. K.

AU - Rangarajan, G.

AU - Srinivasan, R.

PY - 1971/1

Y1 - 1971/1

N2 - Single crystal ESR study of copper diethyldithiocarbamate has shown evidence for the presence of coupled pairs of Cu++ ions. While the g-values for the triplet state remain the same as for the doublet (uncoupled ions), the hyperfine splitting is halved. The zero field splitting parameter D = 276 × 10-4 cm-1. The results have been correlated with crystal structure and susceptibility data.

AB - Single crystal ESR study of copper diethyldithiocarbamate has shown evidence for the presence of coupled pairs of Cu++ ions. While the g-values for the triplet state remain the same as for the doublet (uncoupled ions), the hyperfine splitting is halved. The zero field splitting parameter D = 276 × 10-4 cm-1. The results have been correlated with crystal structure and susceptibility data.

UR - https://www.scopus.com/pages/publications/4644362644

U2 - 10.1016/0009-2614(71)80597-3

DO - 10.1016/0009-2614(71)80597-3

M3 - Article

AN - SCOPUS:4644362644

SN - 0009-2614

VL - 8

SP - 136

EP - 138

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

ESR study of coupled pairs of molecules in copper diethyldithiocarbamate

Abstract

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