Electrophilic Addition to an Iridathiacyclopentene Complex. Synthesis of the First Metallathiophene

John R. Bleeke; Michael F. Ortwerth; Michael Y. Chiang

doi:10.1021/om00028a001

Electrophilic Addition to an Iridathiacyclopentene Complex. Synthesis of the First Metallathiophene

John R. Bleeke
, Michael F. Ortwerth
, Michael Y. Chiang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The reactivity of the unsaturated five-membered iridathiacycle [formula omitted] (1) toward simple electrophiles has been investigated. Protonation occurs at the basic exocyclic methylene carbon, generating [formula omitted], the first example of a “metallathiophene”. In contrast, meth-ylation of 1 occurs at the nucleophilic sulfur center, producing [formula omitted]. X-ray crystal structures of 2a and 3b have been obtained.

Original language	English
Pages (from-to)	985-987
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/om00028a001
State	Published - Apr 1993

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title = "Electrophilic Addition to an Iridathiacyclopentene Complex. Synthesis of the First Metallathiophene",

abstract = "The reactivity of the unsaturated five-membered iridathiacycle [formula omitted] (1) toward simple electrophiles has been investigated. Protonation occurs at the basic exocyclic methylene carbon, generating [formula omitted], the first example of a “metallathiophene”. In contrast, meth-ylation of 1 occurs at the nucleophilic sulfur center, producing [formula omitted]. X-ray crystal structures of 2a and 3b have been obtained.",

author = "Bleeke, \{John R.\} and Ortwerth, \{Michael F.\} and Chiang, \{Michael Y.\}",

year = "1993",

month = apr,

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volume = "12",

pages = "985--987",

journal = "Organometallics",

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T1 - Electrophilic Addition to an Iridathiacyclopentene Complex. Synthesis of the First Metallathiophene

AU - Bleeke, John R.

AU - Ortwerth, Michael F.

AU - Chiang, Michael Y.

PY - 1993/4

Y1 - 1993/4

N2 - The reactivity of the unsaturated five-membered iridathiacycle [formula omitted] (1) toward simple electrophiles has been investigated. Protonation occurs at the basic exocyclic methylene carbon, generating [formula omitted], the first example of a “metallathiophene”. In contrast, meth-ylation of 1 occurs at the nucleophilic sulfur center, producing [formula omitted]. X-ray crystal structures of 2a and 3b have been obtained.

AB - The reactivity of the unsaturated five-membered iridathiacycle [formula omitted] (1) toward simple electrophiles has been investigated. Protonation occurs at the basic exocyclic methylene carbon, generating [formula omitted], the first example of a “metallathiophene”. In contrast, meth-ylation of 1 occurs at the nucleophilic sulfur center, producing [formula omitted]. X-ray crystal structures of 2a and 3b have been obtained.

UR - https://www.scopus.com/pages/publications/0001466276

U2 - 10.1021/om00028a001

DO - 10.1021/om00028a001

M3 - Article

AN - SCOPUS:0001466276

SN - 0276-7333

VL - 12

SP - 985

EP - 987

JO - Organometallics

JF - Organometallics

IS - 4

ER -

Electrophilic Addition to an Iridathiacyclopentene Complex. Synthesis of the First Metallathiophene

Abstract

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