Effect of complexation of zinc(II) on zinc-67 chemical shifts

Gary E. Maciel, Larry Simeral, Joseph J.H. Ackerman

Research output: Contribution to journalArticlepeer-review

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Fourier transform 67Zn NMR spectra were obtained on natural abundance samples. 67Zn chemical shifts are reported for a variety of aqueous Zn(II) solutions. The dependence of the 67Zn chemical shift of a Zn(ClO4)2 solution as a function of added Cl- or Br- is analyzed in terms of relevant complexation equilibria. Chemical shift values of ZnX+, ZnX2, ZnX3-, and ZnX42- species (X = Cl- or Br-) are derived and discussed.

Original languageEnglish
Pages (from-to)263-267
Number of pages5
JournalJournal of Physical Chemistry
Issue number3
StatePublished - Jan 1 1977


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