Effect of complexation of zinc(II) on zinc-67 chemical shifts

Gary E. Maciel; Larry Simeral; Joseph J.H. Ackerman

doi:10.1021/j100518a015

Effect of complexation of zinc(II) on zinc-67 chemical shifts

Gary E. Maciel, Larry Simeral, Joseph J.H. Ackerman

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Abstract

Fourier transform ⁶⁷Zn NMR spectra were obtained on natural abundance samples. ⁶⁷Zn chemical shifts are reported for a variety of aqueous Zn(II) solutions. The dependence of the ⁶⁷Zn chemical shift of a Zn(ClO₄)₂ solution as a function of added Cl^- or Br^- is analyzed in terms of relevant complexation equilibria. Chemical shift values of ZnX⁺, ZnX₂, ZnX₃^-, and ZnX₄^2- species (X = Cl^- or Br^-) are derived and discussed.

Original language	English
Pages (from-to)	263-267
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	81
Issue number	3
DOIs	https://doi.org/10.1021/j100518a015
State	Published - Jan 1 1977

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title = "Effect of complexation of zinc(II) on zinc-67 chemical shifts",

abstract = "Fourier transform 67Zn NMR spectra were obtained on natural abundance samples. 67Zn chemical shifts are reported for a variety of aqueous Zn(II) solutions. The dependence of the 67Zn chemical shift of a Zn(ClO4)2 solution as a function of added Cl- or Br- is analyzed in terms of relevant complexation equilibria. Chemical shift values of ZnX+, ZnX2, ZnX3-, and ZnX42- species (X = Cl- or Br-) are derived and discussed.",

author = "Maciel, {Gary E.} and Larry Simeral and Ackerman, {Joseph J.H.}",

year = "1977",

month = jan,

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doi = "10.1021/j100518a015",

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volume = "81",

pages = "263--267",

journal = "Journal of Physical Chemistry",

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T1 - Effect of complexation of zinc(II) on zinc-67 chemical shifts

AU - Maciel, Gary E.

AU - Simeral, Larry

AU - Ackerman, Joseph J.H.

PY - 1977/1/1

Y1 - 1977/1/1

N2 - Fourier transform 67Zn NMR spectra were obtained on natural abundance samples. 67Zn chemical shifts are reported for a variety of aqueous Zn(II) solutions. The dependence of the 67Zn chemical shift of a Zn(ClO4)2 solution as a function of added Cl- or Br- is analyzed in terms of relevant complexation equilibria. Chemical shift values of ZnX+, ZnX2, ZnX3-, and ZnX42- species (X = Cl- or Br-) are derived and discussed.

AB - Fourier transform 67Zn NMR spectra were obtained on natural abundance samples. 67Zn chemical shifts are reported for a variety of aqueous Zn(II) solutions. The dependence of the 67Zn chemical shift of a Zn(ClO4)2 solution as a function of added Cl- or Br- is analyzed in terms of relevant complexation equilibria. Chemical shift values of ZnX+, ZnX2, ZnX3-, and ZnX42- species (X = Cl- or Br-) are derived and discussed.

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U2 - 10.1021/j100518a015

DO - 10.1021/j100518a015

M3 - Article

AN - SCOPUS:0344345564

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VL - 81

SP - 263

EP - 267

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 3

ER -

Effect of complexation of zinc(II) on zinc-67 chemical shifts

Abstract

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