TY - JOUR
T1 - Dimethyl (±)-(1S*,2R*,3S*)-[3-phenyl-1-(N-phenylcarbamoyloxy)-2, 3-epoxypropyl]-phosphonate
AU - Boehlow, Todd
AU - De La Cruz, Antonette
AU - Rath, Nigam P.
AU - Spilling, Christopher D.
PY - 1997/11/15
Y1 - 1997/11/15
N2 - The crystal structure of the racemic title compound, C18H20NO6P (m.p. 428-431 K), has been determined by X-ray diffraction. The title compound consists of a tetrahedral P atom bonded to two methoxy groups, and an alkyl chain. The alkyl chain is substituted at position 1 with a carbamate and with an epoxide at positions 2 and 3. The relative configuration of the 1-carbamate and 2,3-epoxide substituents was confirmed as anti (1S,2R,3S). The crystal structure contains an enantiomeric pair with two intermolecular hydrogen bonds in a 14-membered ring. The hydrogen bonds are formed between the P=O of one enantiomer and the N-H of the other.
AB - The crystal structure of the racemic title compound, C18H20NO6P (m.p. 428-431 K), has been determined by X-ray diffraction. The title compound consists of a tetrahedral P atom bonded to two methoxy groups, and an alkyl chain. The alkyl chain is substituted at position 1 with a carbamate and with an epoxide at positions 2 and 3. The relative configuration of the 1-carbamate and 2,3-epoxide substituents was confirmed as anti (1S,2R,3S). The crystal structure contains an enantiomeric pair with two intermolecular hydrogen bonds in a 14-membered ring. The hydrogen bonds are formed between the P=O of one enantiomer and the N-H of the other.
UR - https://www.scopus.com/pages/publications/5944240966
M3 - Article
AN - SCOPUS:5944240966
SN - 0108-2701
VL - 53
SP - 1947
EP - 1949
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 11
ER -